Boiling water synthesis of ultrastable thiolated silver nanoclusters with aggregation-induced emission

被引:125
作者
Zheng, Kaiyuan [1 ]
Yuan, Xun [1 ]
Kuah, Kavan [1 ]
Luo, Zhentao [1 ]
Yao, Qiaofeng [1 ]
Zhang, Qingbo [1 ]
Xie, Jianping [1 ]
机构
[1] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 117585, Singapore
关键词
NOBLE-METAL NANOCLUSTERS; AU(I)-THIOLATE COMPLEXES; AG NANOCLUSTERS; LUMINESCENT; GLUTATHIONE; CLUSTERS; GROWTH; IDENTIFICATION; NANOPARTICLES; REDUCTION;
D O I
10.1039/c5cc04858c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A facile boiling water synthesis protocol has been developed to synthesize thiolated Ag nanoclusters with a core-shell Ag(0)@Ag(I)-thiolate structure, which was formed through condensation of Ag(I)-thiolate complexes on the surface of an in situ formed Ag(0) core. The as-synthesized thiolated Ag nanoclusters feature strong luminescence via aggregation-induced-emission (AIE).
引用
收藏
页码:15165 / 15168
页数:4
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