Measurement of chlorine concentration on steel surfaces via fiber-optic laser-induced breakdown spectroscopy in double-pulse configuration

被引：40
|
作者：
Xiao, X. [1 ,2 ]
Le Berre, S. [2 ]
Fobar, D. G. [1 ]
Burger, M. [1 ,4 ]
Skrodzki, P. J. [1 ,4 ]
Hartig, K. C. [2 ,3 ]
Motta, A. T. [2 ]
Jovanovic, I. [1 ,4 ]
机构：
[1] Univ Michigan, Dept Nucl Engn & Radiol Sci, Ann Arbor, MI 48109 USA
[2] Penn State Univ, Dept Mech & Nucl Engn, University Pk, PA 16802 USA
[3] Univ Florida, Nucl Engn Program, Gainesville, FL 32611 USA
[4] Univ Michigan, Ctr Ultrafast Opt Sci, Ann Arbor, MI 48109 USA
来源：
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY | 2018年 / 141卷
关键词：
Laser-induced breakdown spectroscopy (LIBS); Optical fiber; Remote inspection; Double pulse; Chlorine; ELEMENTAL ANALYSIS; PLASMA; CONCRETE; LIBS; ENHANCEMENT; ABLATION; ALLOYS; SYSTEM; PROBE;
D O I：
10.1016/j.sab.2018.01.003
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
The corrosive environment provided by chlorine ions on the welds of stainless steel dry cask storage canisters for used nuclear fuel may contribute to the occurrence of stress corrosion cracking. We demonstrate the use of fiber-optic laser-induced breakdown spectroscopy (FOLIBS) in the double-pulse (DP) configuration for high-sensitivity, remote measurement of the surface concentrations of chlorine compatible in constrained space and challenging environment characteristic for dry cask storage systems. Chlorine surface concentrations as low as 5 mg/m(2) have been detected and quantified by use of a laboratory-based and a fieldable DP FOLIBS setup with the calibration curve approach. The compact final optics assembly in the fieldable setup is interfaced via two 25-m long optical fibers for high-power laser pulse delivery and plasma emission collection and can be readily integrated into a multi-sensor robotic delivery system for in-situ inspection of dry cask storage systems. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码：44 / 52
页数：9
相关论文
共 50 条
  • [1] Double-pulse laser ablation coupled to laser-induced breakdown spectroscopy
    Glaus, Reto
    Hahn, David W.
    SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2014, 98 : 48 - 53
  • [2] Surrogate measurement of chlorine concentration on steel surfaces by alkali element detection via laser-induced breakdown spectroscopy
    Xiao, X.
    Le Berre, S.
    Hartig, K. C.
    Motta, A. T.
    Jovanovic, I.
    SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2017, 130 : 67 - 74
  • [3] Determination of chlorine, sulfur and carbon in reinforced concrete structures by double-pulse laser-induced breakdown spectroscopy
    Labutin, Timur A.
    Popov, Andrey M.
    Zaytsev, Sergey M.
    Zorov, Nikita B.
    Belkov, Mikhail V.
    Kiris, Vasilii V.
    Raikov, Sergey N.
    SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2014, 99 : 94 - 100
  • [4] In situ analysis of steel melt by double-pulse laser-induced breakdown spectroscopy with a Cassegrain telescope
    Sun, Lanxiang
    Yu, Haibin
    Cong, Zhibo
    Xin, Yong
    Li, Yang
    Qi, Lifeng
    SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2015, 112 : 40 - 48
  • [5] In-Situ Analysis of Solid Steel Samples with Remote Double-Pulse Laser-Induced Breakdown Spectroscopy System
    Xin Yong
    Sun Lan-xiang
    Yang Zhi-jia
    Li Yang
    Cong Zhi-bo
    Qi Li-feng
    Zhang Peng
    Zeng Peng
    SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36 (07) : 2255 - 2259
  • [6] The role of plasma shielding in collinear double-pulse femtosecond laser-induced breakdown spectroscopy
    Penczak, John
    Kupfer, Rotem
    Bar, Ilana
    Gordon, Robert J.
    SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2014, 97 : 34 - 41
  • [7] Effect of laser pulse energies in laser induced breakdown spectroscopy in double-pulse configuration
    Benedetti, PA
    Cristoforetti, G
    Legnaioli, S
    Palleschi, V
    Pardini, L
    Salvetti, A
    Tognoni, E
    SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2005, 60 (11) : 1392 - 1401
  • [8] Optimal emission enhancement in orthogonal double-pulse laser-induced breakdown spectroscopy
    Sangines, R.
    Contreras, V.
    Sobral, H.
    Robledo-Martinez, A.
    SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2015, 110 : 139 - 145
  • [9] DOUBLE-PULSE LASER-INDUCED BREAKDOWN SPECTROSCOPY WITH 1030 AND 257.5 nm WAVELENGTH FEMTOSECOND LASER PULSES
    Balachninaite, O.
    Baskevicius, A.
    Stankeviciute, K.
    Kurselis, K.
    Sirutkaitis, V.
    LITHUANIAN JOURNAL OF PHYSICS, 2010, 50 (01): : 105 - 110
  • [10] Double-pulse neodymium YAG/Carbon dioxide laser-induced breakdown spectroscopy for excitation of bulk and trace analytes
    Becker, J. R.
    Skrodzki, P. J.
    Diwakar, P. K.
    Hassanein, A.
    SPECTROSCOPY LETTERS, 2016, 49 (04) : 276 - 284
12345