Room-temperature solid-state synthesis of BiOCl hierarchical microspheres with nanoplates

被引:43
作者
Xie, Jing [1 ]
Cao, Yali [1 ]
Jia, Dianzeng [1 ]
Qin, Haiyu [1 ]
Liang, Zhiting [1 ]
机构
[1] Xinjiang Univ, Inst Appl Chem, Key Lab Mat & Technol Clean Energy, Minist Educ,Key Lab Adv Funct Mat, Urumqi 830046, Xinjiang, Peoples R China
基金
中国国家自然科学基金;
关键词
Solid-state reaction; BiOCl; Microspheres; Photocatalysis; VISIBLE-LIGHT; PHOTOCATALYTIC ACTIVITY; GENERAL STRATEGY; TIO2; DEGRADATION; NANOFIBERS; NANORODS; WATER;
D O I
10.1016/j.catcom.2015.05.007
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The hierarchical BiOCl nanoplates and BiOCl microspheres have been successfully fabricated via a room-temperature solid-state chemical method. It is notable that the polyethylene glycol 400 played an important role for the synthesis of hierarchical BiOCl microspheres, which are assembled by numerous nanoplates with a thickness about 29 nm. Photocatalytic tests showed that the hierarchical BiOCl microspheres exhibit enhanced photocatalytic activity than BiOCl nanoplates under both UV and visible light in degradation of rhodamine B, mainly owing to its novel structure with enlarged specific surface area, enhanced adsorption capacity and exposed {110} faces. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:34 / 38
页数:5
相关论文
共 27 条
[1]   Self-templated synthesis of nanoporous CdS nanostructures for highly efficient photocatalytic hydrogen production under visible [J].
Bao, Ningzhong ;
Shen, Liming ;
Takata, Tsuyoshi ;
Domen, Kazunari .
CHEMISTRY OF MATERIALS, 2008, 20 (01) :110-117
[2]   Photocatalytic and photoelectric properties of cubic Ag3PO4 sub-microcrystals with sharp corners and edges [J].
Bi, Yingpu ;
Hu, Hongyan ;
Ouyang, Shuxin ;
Lu, Gongxuan ;
Cao, Junyu ;
Ye, Jinhua .
CHEMICAL COMMUNICATIONS, 2012, 48 (31) :3748-3750
[3]   Photocatalytic degradation of organic molecules on mesoporous visible-light-active Sn(II)-doped titania [J].
Boppana, Venkata Bharat Ram ;
Lobo, Raul F. .
JOURNAL OF CATALYSIS, 2011, 281 (01) :156-168
[4]   BiOCl nanosheets immobilized on electrospun polyacrylonitrile nanofibers with high photocatalytic activity and reusable property [J].
Chou, Yuechen ;
Shao, Changlu ;
Li, Xinghua ;
Su, Chunyan ;
Xu, Hongchuan ;
Zhang, Mingyi ;
Zhang, Peng ;
Zhang, Xin ;
Liu, Yichun .
APPLIED SURFACE SCIENCE, 2013, 285 :509-516
[5]   A General Strategy to Superstructured Networks and Nested Self-Similar Networks of Bismuth Compounds [J].
Guo, Chuan Fei ;
Zhang, Jianming ;
Tian, Ye ;
Liu, Qian .
ACS NANO, 2012, 6 (10) :8746-8752
[6]   Photocatalytic property of a Bi2O3 nanoparticle modified BiOCl composite with a nanolayered hierarchical structure synthesized by in situ reactions [J].
Hu, Jiajia ;
Xu, Guangqing ;
Wang, Jinwen ;
Lv, Jun ;
Zhang, Xinyi ;
Xie, Ting ;
Zheng, Zhixiang ;
Wu, Yucheng .
DALTON TRANSACTIONS, 2015, 44 (12) :5386-5395
[7]   Engineering the metathesis and oxidation-reduction reaction in solid state at room temperature for nanosynthesis [J].
Hu, Pengfei ;
Cao, Yali ;
Jia, Dianzeng ;
Li, Qiang ;
Liu, Ruili .
SCIENTIFIC REPORTS, 2014, 4
[8]   A Highly Efficient PhotocatalystHydrogenated Black TiO2 for the Photocatalytic Splitting of Water [J].
Hu, Yun Hang .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (50) :12410-12412
[9]   Synthesis of Cu2O Nanocrystals from Cubic to Rhombic Dodecahedral Structures and Their Comparative Photocatalytic Activity [J].
Huang, Wan-Chen ;
Lyu, Lian-Ming ;
Yang, Yu-Chen ;
Huang, Michael H. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (02) :1261-1267
[10]   Synthesis and Facet-Dependent Photoreactivity of BiOCl Single-Crystalline Nanosheets [J].
Jiang, Jing ;
Zhao, Kun ;
Xiao, Xiaoyi ;
Zhang, Lizhi .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (10) :4473-4476