Graphitic Carbon Nitride Hybrid Supported Metal Nanoparticles as a Novel Low-Cost Counter Electrode for Dye-Sensitized Solar Cell

被引:10
作者
Baro, N. Divya Mridula [1 ]
Ramaprabhu, S. [1 ]
机构
[1] Indian Inst Technol Madras, Dept Phys, Alternat Energy & Nanotechnol Lab, Nano Funct Mat Technol Ctr, Madras 600036, Tamil Nadu, India
关键词
Graphene; Graphitic Carbon Nitride; Platinum; Electrocatalyst; DSSC; Counter Electrode; NITROGEN-DOPED GRAPHENE; VISIBLE-LIGHT; HYDROGEN-PRODUCTION; CHARGE-TRANSFER; PERFORMANCE; NANOSHEETS; REDUCTION; NANOTUBES; CATALYST; WATER;
D O I
10.1166/jnn.2016.12147
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the present work we apply the Graphitic carbon nitride-Graphene (Pt-GCN-G) hybrid supported Platinum (Pt) nanoparticles as a novel counter electrode for dye-sensitized solar cell (DSSC). The Pt-GCN-G hybrid is prepared by a facile method and the incorporation of Graphene layers in Graphitic carbon nitride is confirmed from various characterization techniques. The fabricated DSSC with Pt-GCN-G as counter electrode shows an enhanced power conversion efficiency of 5.2%, which is comparable to the standard Pt counter electrode (similar to 6%). The improvement in the electrocatalytic activity of the material has been studied by cyclic voltammetry and electrochemical impedance analysis. The enhancement in the performance of DSSC can be attributed to the synergic effects of GCN, Graphene and Pt nanoparticles.
引用
收藏
页码:9583 / 9590
页数:8
相关论文
共 35 条
  • [1] Pulsed laser deposition of graphite counter electrodes for dye-sensitized solar cells
    Acharya, Krishna P.
    Khatri, Himal
    Marsillac, Sylvain
    Ullrich, Bruno
    Anzenbacher, Pavel
    Zamkov, Mikhail
    [J]. APPLIED PHYSICS LETTERS, 2010, 97 (20)
  • [2] Metal free sensitizer and catalyst for dye sensitized solar cells
    Ahmad, Shahzada
    Guillen, Elena
    Kavan, Ladislav
    Graetzel, Michael
    Nazeeruddin, Mohammad K.
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (12) : 3439 - 3466
  • [3] Impedance characterization of dye-sensitized solar cells in a tandem arrangement for hydrogen production by water splitting
    Andrade, Luisa
    Cruz, Rui
    Ribeiro, Helena Aguilar
    Mendes, Adelio
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (17) : 8876 - 8883
  • [4] Graphene Supported Platinum Nanoparticle Counter-Electrode for Enhanced Performance of Dye-Sensitized Solar Cells
    Bajpai, Reeti
    Roy, Soumyendu
    Kumar, Pragyensh
    Bajpai, Preeti
    Kulshrestha, Neha
    Rafiee, Javad
    Koratkar, Nikhil
    Misra, D. S.
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2011, 3 (10) : 3884 - 3889
  • [5] Perspectives on Carbon Nanotubes and Graphene Raman Spectroscopy
    Dresselhaus, Mildred S.
    Jorio, Ado
    Hofmann, Mario
    Dresselhaus, Gene
    Saito, Riichiro
    [J]. NANO LETTERS, 2010, 10 (03) : 751 - 758
  • [6] Hybrid Graphene and Graphitic Carbon Nitride Nanocomposite: Gap Opening, Electron-Hole Puddle, Interfacial Charge Transfer, and Enhanced Visible Light Response
    Du, Aijun
    Sanvito, Stefano
    Li, Zhen
    Wang, Dawei
    Jiao, Yan
    Liao, Ting
    Sun, Qiao
    Ng, Yun Hau
    Zhu, Zhonghua
    Amal, Rose
    Smith, Sean C.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (09) : 4393 - 4397
  • [7] Covalently coupled hybrid of graphitic carbon nitride with reduced graphene oxide as a superior performance lithium-ion battery anode
    Fu, Yongsheng
    Zhu, Junwu
    Hu, Chong
    Wu, Xiaodong
    Wang, Xin
    [J]. NANOSCALE, 2014, 6 (21) : 12555 - 12564
  • [8] Photoelectrochemical cells
    Grätzel, M
    [J]. NATURE, 2001, 414 (6861) : 338 - 344
  • [9] Dye-sensitized solar cells
    Grätzel, M
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2003, 4 (02) : 145 - 153
  • [10] Dye-Sensitized Solar Cells
    Hagfeldt, Anders
    Boschloo, Gerrit
    Sun, Licheng
    Kloo, Lars
    Pettersson, Henrik
    [J]. CHEMICAL REVIEWS, 2010, 110 (11) : 6595 - 6663