Polymer-copper-modified MWNTs by radiation-induced graft polymerization and their efficient adsorption of odorous gases

被引：4

作者：

Kim, Kyo-Il ^{[1
]}

Oh, Sang-Hyeb ^{[2
]}

Kwen, Hai-Doo ^{[1
]}

Choi, Seong-Ho ^{[1
]}

机构：

[1] Hannam Univ, Dept Chem, Taejon 305811, South Korea

[2] Korea Res Inst Stand & Sci, Taejon 305600, South Korea

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2012年 / 126卷

关键词：

radiation-induced graft polymerization; polymer-copper-modified MWNTs; amine-modified MWNTs; odor gas; MULTIWALLED CARBON NANOTUBES; FUNCTIONALIZATION; MEMBRANES; ELECTRODE; DEVICES;

D O I：

10.1002/app.35453

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polymercopper-modified multi-walled carbon nanotubes (MWNTs) were prepared by radiation-induced graft polymerization of epoxy-containing glycidyl methacrylate and subsequent amination and Cu complexing. Two amines, triethyldiamine and imidazol, were used as polymeric ligand compounds. The Cu-modified MWNTs were confirmed by high-resolution transmittance electron microscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, and thermal gravimetric analysis. The dynamic adsorption of odor gases, such as CH3SH and H2S, on the Cu-modified MWNTs and amine-modified MWNTs was also evaluated. (c) 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012

引用

页码：E64 / E69

页数：6

共 23 条

[21] Functionalization of multiwalled carbon nanotubes with polyamide 6 by anionic ring-opening polymerization [J].