Preparation and characterization of rigid polyurethane foams with carbamide and borate groups

被引:11
|
作者
Zarzyka, Iwona [1 ]
机构
[1] Rzeszow Univ Technol, Dept Organ Chem, Fac Chem, Powstancow Warszawy 6, PL-35929 Rzeszow, Poland
关键词
urea; boric acid; rigid polyurethane foams; flammability reduction; thermal stability; thermal insulation; mechanical strength; 1,3,5-TRIS(2-HYDROXYETHYL) CYANURIC ACID; OIL-BASED POLYOLS; RAPESEED OIL; POLYISOCYANURATE FOAMS; POLYESTER POLYOLS; VEGETABLE-OILS; SOYBEAN-OIL; THERMAL-DECOMPOSITION; DEGRADATION; TEMPERATURE;
D O I
10.1002/pi.5198
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The results of research on the application of hydroxyethyl urea derivatives modified with boron as polyol components to produce foamed polyurethane materials are presented. The obtained rigid polyurethane foams are characterized by good heat-insulating parameters and decreased flammability. The decrease in flammability of the foams follows from the presence of boron and increased nitrogen content, resulting from the use of polyol with urea groups. The incorporation of boron into the foam structure also results in a substantial increase in the compression strength, compared to classic foams and to non-boron-modified ones. The self-extinguishing foams of high mechanical strength can find application as heat-insulating construction elements for the building industry. (c) 2016 Society of Chemical Industry
引用
收藏
页码:1430 / 1440
页数:11
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