BaTiO3-ferrite composites with magnetocapacitance and hard/soft magnetic properties

被引:26
作者
Curecheriu, Lavinia [1 ]
Postolache, Petronel [1 ]
Buscaglia, Vincenzo [2 ]
Horchidan, Nadejda [1 ]
Alexe, Marin [3 ]
Mitoseriu, Liliana [1 ]
机构
[1] Alexandru Ioan Cuza Univ, Dept Phys, Blvd Carol 11, Iasi 700506, Romania
[2] IENI CNR, Inst Energet & Interphases, I-16149 Genoa, Italy
[3] Max Planck Inst Microstruct Phys, D-06120 Halle, Saale, Germany
关键词
magnetocapacitance; dielectric properties; magnetic characteristics; composites; MAGNETOELECTRIC PROPERTIES; RELAXATION; SPECTROSCOPY; IMPEDANCE;
D O I
10.1080/01411594.2012.756879
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
BaTiO3-ferrite multiphase composites were prepared starting from di-phase mixtures of -Fe2O3 and BaTiO3 powders. During the sintering step, the formation of small amounts of secondary phases with multifunctional character as BaFe12O19 or Ba12Ti28Fe15O84 was promoted. The resulting multiphase ceramic compounds show interesting dielectric, magnetic and small magnetocapacitance effect at low temperature. The coexistence of different magnetic phases with contrasting coercivities (hard/soft) was detected by the presence of wasp-waisted' M(H) hysteresis loops and first-order reversal curve analysis. The present approach demonstrates that active materials can be realised by controlling in situ reactions at the interfaces in ferroelectric-magnetic oxide composites.
引用
收藏
页码:670 / 680
页数:11
相关论文
共 33 条
[1]   Electrical properties and magnetoelectric effect in (x)Ni0.5Zn0.5Fe2O4 + (1-x)BPZT composites [J].
Bammannavar, B. K. ;
Naik, L. R. .
SMART MATERIALS AND STRUCTURES, 2009, 18 (08)
[2]   Fe2O3@BaTiO3 Core-Shell Particles as Reactive Precursors for the Preparation of Multifunctional Composites Containing Different Magnetic Phases [J].
Buscaglia, Maria Teresa ;
Buscaglia, Vincenzo ;
Curecheriu, Lavinia ;
Postolache, Petronel ;
Mitoseriu, Liliana ;
Ianculescu, Adelina C. ;
Vasile, Bogdan S. ;
Zhe, Zhao ;
Nanni, Paolo .
CHEMISTRY OF MATERIALS, 2010, 22 (16) :4740-4748
[3]   Physics and Applications of Bismuth Ferrite [J].
Catalan, Gustau ;
Scott, James F. .
ADVANCED MATERIALS, 2009, 21 (24) :2463-2485
[4]   Preparation and magnetoelectric properties of NiFe2O4-PZT composites obtained in-situ by gel-combustion method [J].
Ciomaga, Cristina Elena ;
Airimioaei, Mirela ;
Nica, Valentin ;
Hrib, Luminita M. ;
Caltun, Ovidiu F. ;
Iordan, Alexandra R. ;
Galassi, Carmen ;
Mitoseriu, Liliana ;
Palamaru, Mircea N. .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2012, 32 (12) :3325-3337
[5]   Magnetic and dielectric properties of Ba12Fe28Ti15O84 layered ferrite ceramics [J].
Curecheriu, L. P. ;
Buscaglia, M. T. ;
Ianculescu, A. C. ;
Frunza, R. C. ;
Ciuchi, I. V. ;
Neagu, A. ;
Apachitei, G. ;
Bassano, A. ;
Canu, G. ;
Postolache, P. ;
Mitoseriu, L. ;
Buscaglia, V. .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2011, 44 (43)
[6]   Functional properties of BaTiO3-Ni0.5Zn0.5Fe2O4 magnetoelectric ceramics prepared from powders with core-shell structure [J].
Curecheriu, L. P. ;
Buscaglia, M. T. ;
Buscaglia, V. ;
Mitoseriu, L. ;
Postolache, P. ;
Ianculescu, A. ;
Nanni, P. .
JOURNAL OF APPLIED PHYSICS, 2010, 107 (10)
[7]   Effect of magnetostrictive phase on structural, dielectric and electrical properties of NiFe2O4 + Pb0.93La0.07(Zr0.60Ti0.40)O3 composites [J].
Fawzi, Abdul Samee ;
Sheikh, A. D. ;
Mathe, V. L. .
SOLID STATE SCIENCES, 2009, 11 (11) :1979-1984
[8]   Microstructure and Properties of Well-Ordered Multiferroic Pb(Zr,Ti)O3/CoFe2O4 Nanocomposites [J].
Gao, Xingsen ;
Rodriguez, Brian J. ;
Liu, Lifeng ;
Birajdar, Balaji ;
Pantel, Daniel ;
Ziese, Michael ;
Alexe, Marin ;
Hesse, Dietrich .
ACS NANO, 2010, 4 (02) :1099-1107
[9]   IMPEDANCE AND DIELECTRIC-SPECTROSCOPY REVISITED - DISTINGUISHING LOCALIZED RELAXATION FROM LONG-RANGE CONDUCTIVITY [J].
GERHARDT, R .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1994, 55 (12) :1491-1506
[10]  
HODGE IM, 1976, J ELECTROANAL CHEM, V74, P125, DOI 10.1016/S0022-0728(76)80229-X