Aerobic Ru-catalyzed direct C2-olefination of N-heteroarenes with alkenes directed by a removable N-dimethylcarbamoyl group

被引：76
作者：
Zhang, Luo-Qiang
Yang, Shiping
Huang, Xiaolei
You, Jingsong
Song, Feijie [1 ]
机构：
[1] Sichuan Univ, Key Lab Green Chem & Technol, Minist Educ, Coll Chem, Chengdu 610064, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 78期
关键词：
C-H FUNCTIONALIZATION; N-(2-PYRIDYL)SULFONYL GROUP; BOND FUNCTIONALIZATION; AROMATIC SUBSTITUTION; ORTHO-ALKENYLATION; COUPLING REACTION; OPEN ATMOSPHERE; INDOLES; CARBAZOLE; ACTIVATION;
D O I：
10.1039/c3cc44787a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A highly efficient and selective Ru-catalyzed direct C2-olefination of indoles, pyrroles, and carbazoles assisted by a removable N-dimethylcarbamoyl group has been developed by using O-2 as the terminal oxidant. Both electron-deficient and unactivated alkenes are applicable to the protocol.
引用
收藏
页码：8830 / 8832
页数：3
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