Structural and Dielectric Properties of BaTiO3-NaPO3 Glass-Ceramics

被引：1
作者：
Bih, L. [1 ]
Abbas, L. [1 ]
El Amraoui, Y. [1 ]
Manoun, B. [1 ]
Belhorma, B. [2 ]
Baudin, T. [3 ]
Mezzane, D. [4 ]
机构：
[1] FST Errachidia, PCMI Ceram & Verres, UFR, Errachidia, Morocco
[2] CNESTEN, Maamoura, Morocco
[3] Univ Paris Sud, Lab Physicochim Etat Solide, Paris, France
[4] FST Gueliz, LMCN, Marrakech, Morocco
来源：
FERROELECTRICS | 2008年 / 371卷
关键词：
Barium titanate; ceramics; ferroelectrics;
D O I：
10.1080/00150190802394046
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Glass-ceramics in the system xBaTiO3-(1-x)NaPO3 (0 x 14, x in mol%) have been prepared and characterized. The structural organization of the glass-ceramics has been studied using XRD diffraction and infra-red (FTIR), 31P Magic angle spinning (MAS-NMR) and dielectric spectroscopies. Results suggest two distinct regions comprising the glass structure, one with low-BaTiO3 content and the other with higher content of the ferroelectric compound BaTiO3. The depolymerisation effects and the structure changes, promoted by BaTiO3 addition, are evidenced by means of the IR and NMR results. Dielectric permittivity shows that the ferroelectric-paraelectric transition temperature of each glass-ceramic appears at the same temperature for a pure BaTiO3 ceramic.
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收藏
页码：56 / 62
页数：7
相关论文
共 6 条
[1]   THE SHORT-RANGE STRUCTURE OF SODIUM-PHOSPHATE GLASSES .1. MAS NMR-STUDIES [J].
BROW, RK ;
KIRKPATRICK, RJ ;
TURNER, GL .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1990, 116 (01) :39-45
[2]  
BUM I, 1982, J MATER SCI, V17, P1398
[3]   LIQUID-PHASE SINTERED BATIO3 [J].
CHOWDARY, KR ;
SUBBARAO, EC .
FERROELECTRICS, 1981, 37 (1-4) :689-692
[4]   IR fundamental spectra and structure of pyrophosphate glasses along the 2ZnO center dot P2O5-2Me(2)O center dot P2O5 join (Me being Na and Li) [J].
Efimov, AM .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1997, 209 (03) :209-226
[5]  
KAMITSOS EI, 1995, PHYS CHEM GLASSES, V36, P141
[6]  
VIRKAR AN, 1985, TRANS INDIAN CERAM S, V44, P71
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