The use of solar energy can enhance the conversion of carbon dioxide into energy-rich products: stepping towards artificial photosynthesis

被引:41
作者
Aresta, Michele [2 ]
Dibenedetto, Angela [1 ,2 ]
Angelini, Antonella [1 ,2 ]
机构
[1] Univ Bari, Dept Chem, I-70126 Bari, Italy
[2] CIRCC, I-70126 Bari, Italy
来源
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 2013年 / 371卷 / 1996期
关键词
carbon dioxide; energy products; chemicals; solar energy; photovoltaic; photochemical; ELECTROCATALYTIC REDUCTION; CO2; METHANOL; WATER; CATALYSIS; NICKEL;
D O I
10.1098/rsta.2012.0111
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The need to cut CO2 emission into the atmosphere is pushing scientists and technologists to discover and implement new strategies that may be effective for controlling the CO2 atmospheric level (and its possible effects on climate change). One option is the capture of CO2 from power plant flue gases or other industrial processes to avoid it entering the atmosphere. The captured CO2 can be either disposed in natural fields (geological cavities, spent gas or oil wells, coal beads, aquifers; even oceans have been proposed) or used as a source of carbon in synthetic processes. In this paper, we present the options for CO2 utilization and make an analysis of possible solutions for the conversion of large volumes of CO2 by either combining it with H-2, that must be generated from water, or by directly converting it into fuels by electrolysis in water using solar energy. A CO2-H-2-based economy may address the issue of reducing the environmental burden of energy production, also saving fossil carbon for future generations. The integration of CO2 capture and utilization with CO2 capture and storage would result in a more economically and energetically viable practice of CO2 capture.
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页数:18
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