An efficient method for selective deprotection of trimethylsilyl ethers and tetrahydropyranyl ethers under solvent-free conditions

被引：0

作者：

Hajipour, AR

Bagheri, HR

Ruoho, AE

机构：

[1] Univ Wisconsin, Sch Med, Dept Pharmacol, Madison, WI 53706 USA

[2] Isfahan Univ Technol, Dept Chem, Pharmaceut Res Lab, Esfahan 84156, Iran

来源：

BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2005年 / 26卷 / 11期

关键词：

deprotection; trimethylsilyl ether; tetrahydropyranyl ethers; solvent-free;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1-Butyl-4-aza-1-azoniabicyclo[2.2.2]octane dichromate (BAABOD) 3 is a useful reagent for the selective cleavage of trimethylsilyl ethers and tetrahydropyranyl ethers to their corresponding aldehydes and ketones in the presence of AlCl3 under solvent-free conditions. This method is very simple and efficient and the reaction has been carried out under solvent-free conditions in the presence of a catalytically amount of aluminum chloride.

引用

页码：1689 / 1691

页数：3

共 27 条

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