Onion-like carbon nanoparticles generated by multiple laser irradiations on laser-ablated particles

被引:15
作者
Inoue, Ayumi [1 ]
Seto, Takafumi [1 ]
Otani, Yoshio [1 ]
机构
[1] Kanazawa Univ, Dept Chem & Mat Engn, Kanazawa, Ishikawa 9201192, Japan
关键词
POLYHEDRAL PARTICLES; TRANSFORMATION; POWER;
D O I
10.1016/j.carbon.2011.10.024
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A one-step process to synthesize onion-like carbon nanoparticles at room temperature under atmospheric pressure was developed. Periodic pulsed laser irradiation of carbon nanoparticles confined in the cavity of a carbon target rod induces drastic changes to their structure, changing them from amorphous to ordered concentric graphitic shells. The size distribution of gas-borne nanoparticles measured by a scanning mobility particle sizer showed the mean mobility diameter decreased from 83 nm to 18 nm as a result of restructuring of carbon agglomerates. Polyhedral and unagglomerated nanoparticles with shell structures composed of multiple graphene sheets were observed by a transmission electron microscopy. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1116 / 1122
页数:7
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