Crystalline phosphino(silyl)carbenes that readily form transition metal complexes

被引：3
作者：
Loewe, Pawel [1 ]
Dielmann, Fabian [2 ]
机构：
[1] Westfalische Wilhelms Univ Munster, Inst Anorgan & Analyt Chem, Corrensstr 30, D-48149 Munster, Germany
[2] Leopold Franzens Univ Innsbruck, Inst Gen Inorgan & Theoret Chem, Innrain 80-82, A-6020 Innsbruck, Austria
来源：
CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 84期
关键词：
LEWIS-BASE-FREE; SELECTIVE SEMIHYDROGENATION; ELECTRONIC-STRUCTURE; H BONDS; LIGANDS; REACTIVITY; PHOSPHINE; CARBENES; ALKYNES;
D O I：
10.1039/d2cc04321a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Phosphino(silyl)carbenes are known for their ineptitude to form transition metal complexes. We describe the synthesis of phosphino(silyl)carbenes bearing N-heterocyclic imine groups and show that these isolable, crystalline carbenes readily form stable copper(i) and gold(i) complexes. The solid-state structures of the free carbenes and their transition metal complexes are reported.
引用
收藏
页码：11831 / 11834
页数：4
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