Comparison of thin-film and bulk CuIn1-xGaxSe2 samples by laser induced breakdown spectroscopy

被引:3
作者
Kim, Chan K. [1 ]
Lee, Seok H. [1 ]
In, Jung H. [1 ]
Shim, Hee-S. [2 ]
Kim, Dong S. [1 ]
Jeong, Sungho [1 ]
机构
[1] Gwangju Inst Sci & Technol, Sch Mechatron, Kwangju 500712, South Korea
[2] Gwangju Inst Sci & Technol, Res Inst Solar & Sustainable Energies, Kwangju 500712, South Korea
关键词
CIGS; Thin film; Solar cell; Laser induced breakdown spectroscopy (LIBS); OPTICAL-PROPERTIES; SPECTROMETRY;
D O I
10.1016/j.tsf.2013.04.068
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The results for laser induced breakdown spectroscopy (LIBS) measurements of CuIn1-xGaxSe2 (CIGS) thin film samples deposited on Mo-coated soda-lime glass by co-evaporation technique and those of bulk form CIGS targets are reported. The LIBS intensity calibration results for the thin film and bulk CIGS samples were compared with respect to the concentration ratios. While the concentrations for thin film CIGS samples were measured by X-ray fluorescence, the compositions of bulk samples were provided by the manufacturer. It was found that the calibration results of Ga/(Ga + In) ratio obtained from the thin film and bulk form samples showed a good agreement at optimized measurement conditions. It is demonstrated that bulk samples can provide reliable reference composition data for the elemental analysis of thin CIGS films. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:393 / 397
页数:5
相关论文
共 19 条
[1]   LASER MICROSPECTRAL ANALYSIS - A REVIEW OF PRINCIPLES AND APPLICATIONS [J].
ADRAIN, RS ;
WATSON, J .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1984, 17 (10) :1915-+
[2]   Optical functions of chalcopyrite CuGaxIn1-xSe2 alloys [J].
Alonso, MI ;
Garriga, M ;
Rincón, CAD ;
Hernández, E ;
León, M .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2002, 74 (05) :659-664
[3]   Laser-induced breakdown spectroscopy in industrial and security applications [J].
Bol'shakov, Alexander A. ;
Yoo, Jong H. ;
Liu, Chunyi ;
Plumer, John R. ;
Russo, Richard E. .
APPLIED OPTICS, 2010, 49 (13) :C132-C142
[4]   Surface stoichiometry of manganin coatings prepared by pulsed laser deposition as described by laser-induced breakdown spectrometry [J].
Cabalín, LM ;
Laserna, JJ .
ANALYTICAL CHEMISTRY, 2001, 73 (06) :1120-1125
[5]   Laser-Induced Breakdown Spectroscopy-Capabilities and Limitations [J].
Cremers, David A. ;
Chinni, Rosemarie C. .
APPLIED SPECTROSCOPY REVIEWS, 2009, 44 (06) :457-506
[6]   In situ X-ray fluorescence used for real-time control of CuInxGa1-xSe2 thin film composition [J].
Eisgruber, IL ;
Joshi, B ;
Gomez, N ;
Britt, J ;
Vincent, T .
THIN SOLID FILMS, 2002, 408 (1-2) :64-72
[7]   Laser-Induced Breakdown Spectroscopy (LIBS), Part II: Review of Instrumental and Methodological Approaches to Material Analysis and Applications to Different Fields [J].
Hahn, David W. ;
Omenetto, Nicolo .
APPLIED SPECTROSCOPY, 2012, 66 (04) :347-419
[8]   Effect of Cu deficiency on the optical properties and electronic structure of CuIn1-xGaxSe2 [J].
Han, SH ;
Hasoon, FS ;
Al-Thani, HA ;
Hermann, AM ;
Levi, DH .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2005, 66 (11) :1895-1898
[9]   New world record efficiency for Cu(In,Ga)Se2 thin-film solar cells beyond 20% [J].
Jackson, Philip ;
Hariskos, Dimitrios ;
Lotter, Erwin ;
Paetel, Stefan ;
Wuerz, Roland ;
Menner, Richard ;
Wischmann, Wiltraud ;
Powalla, Michael .
PROGRESS IN PHOTOVOLTAICS, 2011, 19 (07) :894-897
[10]   Influence of molybdenum layer on the laser plasma generated from interfacing copper layer [J].
Kim, Chan K. ;
Kim, Dong S. ;
Lee, Seok H. ;
Shim, Hee-S. ;
Jeong, Sungho .
APPLIED OPTICS, 2012, 51 (07) :B93-B98