Synthesis of isoquinolone via rhodium(III)-catalyzed C-H activation with 1,4,2-dioxazol-5-ones as oxidizing directing group

被引：15
|
作者：
Zhu, Huajian [1 ]
Zhuang, Rangxiao [2 ]
Zheng, Wenya [1 ]
Fu, Liping [3 ]
Zhao, Yuanke [1 ]
Tu, Luping [1 ]
Chai, Yitao [1 ]
Zeng, Linghui [1 ]
Zhang, Chong [1 ]
Zhang, Jiankang [1 ]
机构：
[1] Zhejiang Univ City Coll, Sch Med, Hangzhou 310015, Zhejiang, Peoples R China
[2] Hangzhou Xixi Hosp, Dept Pharmaceut Preparat, Hangzhou 310023, Zhejiang, Peoples R China
[3] Shaoxing Hosp Tradit Chinese Med, Dept Pharm, Shaoxing 312000, Zhejiang, Peoples R China
来源：
TETRAHEDRON | 2019年 / 75卷 / 23期
基金：
美国国家科学基金会;
关键词：
1,4,2-Dioxazol-5-ones; Rhodium(III)-catalyzed; C-H activation; Oxidizing directing groups; Isoquinolones; OXIDATIVE ANNULATION; CATALYZED SYNTHESIS; INTERNAL OXIDANT; DIRECT ACCESS; O BOND; BENZAMIDES; AMIDATION; ACTIVATION/ANNULATION; CYCLOADDITION; ALKENYLATION;
D O I：
10.1016/j.tet.2019.04.054
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient rhodium-catalyzed direct C-H activation for the synthesis of isoquinolone with 1,4,2-dioxazol-5-ones as oxidizing directing groups have been developed, which featured mild reaction conditions, short reaction time and satisfactory yield. (C) 2019 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3108 / 3112
页数：5
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