Synthesis and structures of two new coordination polymers formed by large polyoxometalate fragments and lanthanide cations

被引：8

作者：

Izarova, N. V. ^{[1
]}

Sokolov, M. N. ^{[1
]}

Samsonenko, D. G. ^{[1
]}

Rothenberger, A. ^{[2
]}

Fenske, D. ^{[2
]}

Fedin, V. P. ^{[1
]}

机构：

[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

[2] Univ Karlsruhe, Inst Inorgan Chem, D-76128 Karlsruhe, Germany

来源：

RUSSIAN CHEMICAL BULLETIN | 2008年 / 57卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

polyoxometalates; coordination polymers; molybdenum; lanthanides; crystal structure;

D O I：

10.1007/s11172-008-0011-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of the polyoxometalate [Mo36O108(NO)(4)(H2O)(16)](12-) with EuCl3 center dot 6H(2)O and Tm-2(SO4)(3) center dot 8H(2)O afford the coordination polymers with the following composition: (H3O)(3.67){Eu(H2O)(4)}{Eu(H2O)(6)}(2) {Mo-36(NO)(4)O-108(H2O)(16))}Cl-0.67 center dot 29.5H(2)O and (H3O)(5) [{Tm(H2O)(6)}(2){Tm(H2O)} {Mo-36(NO)(4)O-108(H2O)(16)}]Cl-2 center dot 45H(2)O, respectively, in which the polyoxometalate fragments are linked to each other by lanthanide cations to form infinite chains.

引用

页码：78 / 82

页数：5

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