Design and construction of supramolecular polysulfurated metallodendrimers with various shapes and sizes via coordination-driven self-assembly

被引：16
作者：
Wu, Nai-Wei [1 ]
Li, Quan-Jie [2 ]
Zhang, Jing [1 ]
He, Jiuming [3 ,4 ]
Ou-Yang, Jiang-Kun [1 ]
Tan, Hongwei [2 ]
Abliz, Zeper [3 ,4 ]
Yang, Hai-Bo [1 ]
机构：
[1] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
[2] Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China
[3] Chinese Acad Med Sci, Inst Mat Med, Beijing 100050, Peoples R China
[4] Peking Union Med Coll, Beijing 100050, Peoples R China
来源：
TETRAHEDRON | 2013年 / 69卷 / 29期
关键词：
DENDRITIC MULTIFERROCENYL HEXAGONS; TRIS(CROWN ETHER) HEXAGONS; MOLECULAR ARCHITECTURE; DENDRIMERS; COMPLEXES; CHEMISTRY; CAGE; GUESTS; ELECTRONICS; LUMINESCENT;
D O I：
10.1016/j.tet.2013.04.058
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new family of 120 degrees polysulfurated dipyridine donors have been successfully designed and synthesized, from which a series of novel rhomboidal and hexagonal supramolecular polysulfurated metallodendrimers were prepared via coordination-driven self-assembly. The structures of the newly designed polysulfurated metallodendrimers were characterized by multinuclear NMR (H-1 and P-31), mass spectrometry (CSI-TOF-MS), and elemental analysis. Moreover, the shape and size of these novel metallodendrimers were investigated with PM6 semi-empirical molecular orbital methods. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5981 / 5988
页数：8
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