Design and construction of supramolecular polysulfurated metallodendrimers with various shapes and sizes via coordination-driven self-assembly

被引：16

作者：

Wu, Nai-Wei ^{[1
]}

Li, Quan-Jie ^{[2
]}

Zhang, Jing ^{[1
]}

He, Jiuming ^{[3
,4
]}

Ou-Yang, Jiang-Kun ^{[1
]}

Tan, Hongwei ^{[2
]}

Abliz, Zeper ^{[3
,4
]}

Yang, Hai-Bo ^{[1
]}

机构：

[1] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

[2] Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China

[3] Chinese Acad Med Sci, Inst Mat Med, Beijing 100050, Peoples R China

[4] Peking Union Med Coll, Beijing 100050, Peoples R China

来源：

TETRAHEDRON | 2013年 / 69卷 / 29期

关键词：

DENDRITIC MULTIFERROCENYL HEXAGONS; TRIS(CROWN ETHER) HEXAGONS; MOLECULAR ARCHITECTURE; DENDRIMERS; COMPLEXES; CHEMISTRY; CAGE; GUESTS; ELECTRONICS; LUMINESCENT;

D O I：

10.1016/j.tet.2013.04.058

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new family of 120 degrees polysulfurated dipyridine donors have been successfully designed and synthesized, from which a series of novel rhomboidal and hexagonal supramolecular polysulfurated metallodendrimers were prepared via coordination-driven self-assembly. The structures of the newly designed polysulfurated metallodendrimers were characterized by multinuclear NMR (H-1 and P-31), mass spectrometry (CSI-TOF-MS), and elemental analysis. Moreover, the shape and size of these novel metallodendrimers were investigated with PM6 semi-empirical molecular orbital methods. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：5981 / 5988

页数：8

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