Steric structure of bis(5,5-dimethyl-3-thioxo-1-cyclohexenyl) sulfide

被引：1

作者：

Kanitskaya, LV ^{[1
]}

Timokhina, LV ^{[1
]}

Panova, GM ^{[1
]}

Fedorov, SV ^{[1
]}

Aksamentova, TN ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Div, Favorskii Irkutsk Inst Chem, Irkutsk 664003, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2002年 / 72卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

Spectroscopy; Sulfide; Dipole Moment; Moment Measurement; Steric Structure;

D O I：

10.1023/A:1015345328968

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two-dimensional NMR spectroscopy, dipole moment measurements, and quantum-chemical calculations (basis 6-31G*) were used to show that in the gas phase and in solutions bis(5,5-dimethyl-3-thioxo-1-cyclohexenyl) sulfide prefers a nonplanar cis-trans conformation.

引用

页码：71 / 74

页数：4

共 10 条

[1] FRISCH MJ, 1995, GAUSSIAN 94 REV E 3
[2] A SYSTEMATIC-APPROACH TO CALCULATE MOLECULAR-PROPERTIES OF ORGANOSULFUR COMPOUNDS CONTAINING THE CSP2-S BOND
KAO, J
EYERMANN, C
SOUTHWICK, E
LEISTER, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (19) : 5323 - 5332
[3] MINKIN VI, 1968, DIPOLNYE MEMENTY ORG
[4] REMIZOV AB, 1975, ZH OBSHCH KHIM+, V45, P1402
[5] REMIZOV AB, 1976, ZH PRIKL SPEKTROSK, V25, P748
[6] Sinegovskaya LM, 1996, USP KHIM+, V65, P1091
[7] INFRARED-SPECTRUM OF DIVINYL TELLURIDE AND THEORETICAL-ANALYSIS OF DIVINYL GROUP-VI COMPOUNDS
SOHLBERG, K
BAKER, BL
LEARY, SP
OWEN, NL
FACELLI, JC
TROFIMOV, BA
[J]. JOURNAL OF MOLECULAR STRUCTURE, 1995, 354 (01) : 55 - 69
[8] TIMOKHINA LV, 1978, ZH ORG KHIM+, V14, P2226
[9] Timokhina LV, 1999, ZH ORG KHIM+, V35, P1436
[10] DIPOLE ASSOCIATION
TREINER, C
FUOSS, RM
SKINNER, JF
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (11) : 3406 - &

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