Nitrogen-Doped Carbon Nanocages as Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction

被引:724
作者
Chen, Sheng [1 ,2 ]
Bi, Jiyu [1 ,2 ]
Zhao, Yu [1 ,2 ]
Yang, Lijun [1 ,2 ]
Zhang, Chen [1 ,2 ]
Ma, Yanwen [3 ]
Wu, Qiang [1 ,2 ]
Wang, Xizhang [1 ,2 ]
Hu, Zheng [1 ,2 ]
机构
[1] Nanjing Univ, Key Lab Mesoscop Chem MOE, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China
[2] Nanjing Univ, Jiangsu Prov Lab Nanotechnol, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China
[3] Nanjing Univ Posts & Telecommun, Jiangsu Key Lab Organ Elect & Informat Displays, Inst Adv Mat, Nanjing 210046, Jiangsu, Peoples R China
关键词
metal-free electrocatalysts; oxygen reduction reaction; nitrogen-doped carbon nanocages; high specific surface area; fuel cells; FUEL-CELL; NANOTUBES; CATALYST; ELECTRODE; GRAPHENE; BORON;
D O I
10.1002/adma.201202424
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Metal-free ORR Electrocatalysts: N-doped carbon nanocages (NCNCs) with large specific surface areas of up to 1393 m(2) g(-1), which demonstrate excellent ORR performance with high activity, are produced for the first time. Without the interference of any ORR-active metal impurities in NCNCs, the experimental results confirm that the ORR activity originates from the N-doped carbon species.
引用
收藏
页码:5593 / 5597
页数:5
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