Nanocomposite NiO:Au hydrogen sensors with high sensitivity and low operating temperature

被引:18
作者
Kandyla, M. [1 ]
Chatzimanolis-Moustakas, C. [1 ,2 ]
Koumoulos, E. P. [2 ]
Charitidis, C. [2 ]
Kompitsas, M. [1 ]
机构
[1] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, GR-11635 Athens, Greece
[2] Natl Tech Univ Athens, Sch Chem Engn, Zografos 15780, Greece
关键词
Composites; Oxides; Sputtering; Laser deposition; Electrochemical properties; H-2 SENSING PROPERTIES; THIN-FILM; ENHANCEMENT; GROWTH;
D O I
10.1016/j.materresbull.2013.09.044
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present results on the development of nanocomposite NiO:Au thin-film hydrogen sensors, which are able to detect hydrogen concentrations as low as 2 ppm in air, operating at low temperatures in the range 125-150 degrees C. Thin NiO films were sputter-deposited on oxidized silicon substrates. The structural, morphological, and nanomechanical properties of the films were investigated with respect to post-deposition annealing. Au nanoparticles were added on the NiO surface via pulsed laser deposition and the films were tested as hydrogen sensors before and after Au deposition. The performance of the NiO films as hydrogen sensors improved significantly in the presence of Au nanoparticles on the surface. The detection limit (lowest detectable hydrogen concentration) decreased by two orders of magnitude, while the response time also decreased by a factor of three. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:552 / 559
页数:8
相关论文
共 42 条
[1]   Electrical and optical properties of narrow-band materials [J].
Adler, David ;
Feinleib, Julius .
PHYSICAL REVIEW B-SOLID STATE, 1970, 2 (08) :3112-3134
[2]   Gas sensing properties of defect-controlled ZnO-nanowire gas sensor [J].
Ahn, M. -W. ;
Park, K. -S. ;
Heo, J. -H. ;
Park, J. -G. ;
Kim, D. -W. ;
Choi, K. J. ;
Lee, J. -H. ;
Hong, S. -H. .
APPLIED PHYSICS LETTERS, 2008, 93 (26)
[3]   The gas response enhancement from ZnO film for H2 gas detection [J].
Al-Hardan, N. ;
Abdullah, M. J. ;
Aziz, A. Abdul .
APPLIED SURFACE SCIENCE, 2009, 255 (17) :7794-7797
[4]   Pd-Sensitized Single Vanadium Oxide Nanowires: Highly Responsive Hydrogen Sensing Based on the Metal-insulator Transition [J].
Baik, Jeong Min ;
Kim, Myung Hwa ;
Larson, Christopher ;
Yavuz, Cafer T. ;
Stucky, Galen D. ;
Wodtke, Alec M. ;
Moskovits, Martin .
NANO LETTERS, 2009, 9 (12) :3980-3984
[5]   Modeling of sensing and transduction for p-type semiconducting metal oxide based gas sensors [J].
Barsan, N. ;
Simion, C. ;
Heine, T. ;
Pokhrel, S. ;
Weimar, U. .
JOURNAL OF ELECTROCERAMICS, 2010, 25 (01) :11-19
[6]   Influence of indenter tip geometry on elastic deformation during nanoindentation [J].
Bei, H ;
George, EP ;
Hay, JL ;
Pharr, GM .
PHYSICAL REVIEW LETTERS, 2005, 95 (04)
[7]   Nanomechanical and nanotribological properties of carbon-based thin films: A review [J].
Charitidis, C. A. .
INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 2010, 28 (01) :51-70
[8]   Thin-film heterostructure solid oxide fuel cells [J].
Chen, X ;
Wu, NJ ;
Smith, L ;
Ignatiev, A .
APPLIED PHYSICS LETTERS, 2004, 84 (14) :2700-2702
[9]   Gas sensing properties of p-type hollow NiO hemispheres prepared by polymeric colloidal templating method [J].
Cho, Nam Gyu ;
Hwang, In-Sung ;
Kim, Ho-Gi ;
Lee, Jong-Heun ;
Kim, Il-Doo .
SENSORS AND ACTUATORS B-CHEMICAL, 2011, 155 (01) :366-371
[10]   H2 sensing properties in highly oriented SnO2 thin films [J].
Choi, Yun-Hyuk ;
Hong, Seong-Hyeon .
SENSORS AND ACTUATORS B-CHEMICAL, 2007, 125 (02) :504-509