Copper-Mediated Reaction of Zirconacyclopentadienes with Azides: A One-Pot Three-Component Synthesis of Multiply Substituted Pyrroles from One Azide and Two Alkynes

被引：14
|
作者：
Zhou, Yiqing [1 ]
Yan, Xiaoyu [1 ]
Chen, Chao [1 ]
Xi, Chanjuan [1 ,2 ]
机构：
[1] Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Minist Educ, Beijing 100084, Peoples R China
[2] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
来源：
ORGANOMETALLICS | 2013年 / 32卷 / 21期
基金：
中国国家自然科学基金;
关键词：
METAL-PROMOTED CYCLIZATION; CYCLOADDITION REACTION; METALLACYCLE TRANSFER; BENZENE-DERIVATIVES; CONVENIENT METHOD; SULFONYL AZIDE; ZIRCONOCENE; PATHWAY; ZIRCONACYCLES; ZIRCONIUM;
D O I：
10.1021/om400988g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A general method for the synthesis of multiply substituted pyrroles through zirconocene-mediated coupling of two alkynes and an azide in the presence of CuCl has been achieved.
引用
收藏
页码：6182 / 6185
页数：4
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