C-3-symmetric tripodal tetra-amines - preparation from chiral amino alcohols via aziridines

被引：63

作者：

Cernerud, M ^{[1
]}

Adolfsson, H ^{[1
]}

Moberg, C ^{[1
]}

机构：

[1] ROYAL INST TECHNOL,DEPT CHEM,S-10044 STOCKHOLM,SWEDEN

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 15期

基金：

瑞典研究理事会;

关键词：

D O I：

10.1016/S0957-4166(97)00302-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantiopure N-sulfonylaziridines, conveniently obtained from readily available enantiopure amino alcohols, undergo smooth ring opening reactions using ammonia as a nucleophile to yield tripodal tetradentate C-3-symmetric amines. N-alkylation and subsequent removal of the sulfonyl groups provide access to alkyl-substituted analogs. (C) 1997 Elsevier Science Ltd.

引用

页码：2655 / 2662

页数：8

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