A facile channel for D-glucose detection in aqueous solution

被引：18
|
作者：
Wang, Zhijun [1 ]
Lei, Haiying [2 ]
Feng, Liheng [3 ]
机构：
[1] Changzhi Univ, Dept Chem, Changzhi 046011, Peoples R China
[2] Changzhi Univ, Dept Biol Sci & Technol, Changzhi 046011, Peoples R China
[3] Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Peoples R China
来源：
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2013年 / 114卷
关键词：
Chemosensor; D-glucose; Dye; Boronic acid; Viologens; Ensemble; ACID-SUBSTITUTED VIOLOGENS; BORONIC ACID; MONOSACCHARIDE DETECTION; SACCHARIDE DETECTION; BIPYRIDINIUM SALTS; FLUORESCENT SENSOR; CHEMICAL SENSORS; D-FRUCTOSE; CHEMOSENSORS; RECOGNITION;
D O I：
10.1016/j.saa.2013.05.089
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
Three facile ensembles for sensing D-glucose are designed and constructed. The ensembles are comprised of fluorescent dye (NAHBDS) and boronic acid substituted viologens (BBVs) quenchers/receptors. The sensing processes of three ensembles (NAHBDS/o-BBV, NAHBDS/m-BBV and NAHBDS/p-BBV) to D-glucose were determined by fluorescence spectra at pH 7.4 buffer solution. The results show that NAHBDS/o-BBV and NAHBDS/m-BBV ensembles embody higher sensitivity for D-glucose with reversible "on-off" fluorescence response. More importantly, the recovery of relative intensity has good linear relation to low concentration of D-glucose. The action between the ensemble with D-glucose is dynamically reversible equilibrium process. The research results provide a new mode to design highly selective probe. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：293 / 297
页数：5
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