共 29 条
A facile channel for D-glucose detection in aqueous solution
被引:18
作者:

Wang, Zhijun
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h-index: 0
机构:
Changzhi Univ, Dept Chem, Changzhi 046011, Peoples R China Changzhi Univ, Dept Chem, Changzhi 046011, Peoples R China

Lei, Haiying
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h-index: 0
机构:
Changzhi Univ, Dept Biol Sci & Technol, Changzhi 046011, Peoples R China Changzhi Univ, Dept Chem, Changzhi 046011, Peoples R China

Feng, Liheng
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h-index: 0
机构:
Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Peoples R China Changzhi Univ, Dept Chem, Changzhi 046011, Peoples R China
机构:
[1] Changzhi Univ, Dept Chem, Changzhi 046011, Peoples R China
[2] Changzhi Univ, Dept Biol Sci & Technol, Changzhi 046011, Peoples R China
[3] Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Peoples R China
关键词:
Chemosensor;
D-glucose;
Dye;
Boronic acid;
Viologens;
Ensemble;
ACID-SUBSTITUTED VIOLOGENS;
BORONIC ACID;
MONOSACCHARIDE DETECTION;
SACCHARIDE DETECTION;
BIPYRIDINIUM SALTS;
FLUORESCENT SENSOR;
CHEMICAL SENSORS;
D-FRUCTOSE;
CHEMOSENSORS;
RECOGNITION;
D O I:
10.1016/j.saa.2013.05.089
中图分类号:
O433 [光谱学];
学科分类号:
0703 ;
070302 ;
摘要:
Three facile ensembles for sensing D-glucose are designed and constructed. The ensembles are comprised of fluorescent dye (NAHBDS) and boronic acid substituted viologens (BBVs) quenchers/receptors. The sensing processes of three ensembles (NAHBDS/o-BBV, NAHBDS/m-BBV and NAHBDS/p-BBV) to D-glucose were determined by fluorescence spectra at pH 7.4 buffer solution. The results show that NAHBDS/o-BBV and NAHBDS/m-BBV ensembles embody higher sensitivity for D-glucose with reversible "on-off" fluorescence response. More importantly, the recovery of relative intensity has good linear relation to low concentration of D-glucose. The action between the ensemble with D-glucose is dynamically reversible equilibrium process. The research results provide a new mode to design highly selective probe. (C) 2013 Elsevier B.V. All rights reserved.
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页码:293 / 297
页数:5
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