Proton Conduction in Highly Textured Y:BaZrO3 and Y:BaZrCeO3 Thin Films Fabricated by Pulsed Laser Deposition

被引:3
作者
Bae, K. [1 ]
Choi, S. M.
Hwang, J.
Son, J. -W.
Shim, J. H. [1 ]
机构
[1] Korea Univ, Dept Mech Engn, Seoul 136701, South Korea
来源
IONIC AND MIXED CONDUCTING CERAMICS 8 | 2012年 / 45卷 / 01期
关键词
DOPED BARIUM ZIRCONATE;
D O I
10.1149/1.3701301
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Highly textured BZY and BZCY films were fabricated on a single crystalline MgO(100) substrate by PLD under various deposition conditions including substrate temperature and target-to-substrate distance. The perovskite-type oxides, BaZr0.85Y0.15O3-delta (BZY) and BaZr0.3Ce0.55Y0.15O3-delta (BZCY), were synthesized via a solid-state reaction method and sintered at 1680 degrees C to be used as targets for pulsed laser deposition (PLD). The structural properties of the films were analyzed by x-ray diffraction (XRD) and scanning electron microscopy (SEM). The electrical conductivities of the films were measured by the electrochemical impedance spectroscopy (EIS) method in the temperature range of 220-460 degrees C.
引用
收藏
页码:129 / 133
页数:5
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