Studies on green and efficient catalytic oxidation of a triazole compound

被引：1

作者：

Luo, J. ^{[1
]}

Liu, Y. C. ^{[1
]}

Huang, K. H. ^{[2
]}

Chai, T. ^{[1
]}

Wang, J. H. ^{[1
]}

Yu, Y. W. ^{[1
]}

Yuan, J. M. ^{[1
]}

Chang, S. J. ^{[1
]}

Guo, J. H. ^{[1
]}

Zhang, J. ^{[1
,3
]}

机构：

[1] North Univ China, Sch Chem Engn & Environm, Taiyuan 030051, Peoples R China

[2] Longhui Vocat & Tech Inst, Shaoyang 422200, Peoples R China

[3] Hubei Space Sanjiang Honglin Detect & Control Co, Xiaogan 432000, Peoples R China

来源：

2016 GLOBAL CONFERENCE ON POLYMER AND COMPOSITE MATERIALS (PCM 2016) | 2016年 / 137卷

关键词：

HYDROGEN-PEROXIDE; METAL CATALYSIS; MOLYBDENUM; TUNGSTEN; ALCOHOLS; DESULFURIZATION; COMPLEXES;

D O I：

10.1088/1757-899X/137/1/012064

中图分类号：

TB33 [复合材料];

学科分类号：

摘要：

1-Methyl-3,5-dinitro-1,2,4-triazole is an insensitive energetic compound that can be prepared by oxidizing the nitrate salt of 1-methylguanazole. The influence of the reaction time, reaction temperature, reactant ratio, feeding method and catalytic oxidation method on the yield were discussed. The results show that the optimum reaction conditions are as follows: mass ratio of sodium tungstate to nitrate salt to 1-methylguanazole, 4:4.4; time, 5.5h; and temperature, 65-75 degrees C. The yield of this oxidation reaction reached 51.36%.

引用

页数：5

共 15 条

[1] METAL CATALYSIS IN OXIDATION BY PEROXIDES .25. MOLYBDENUM-CATALYZED AND TUNGSTEN-CATALYZED OXIDATIONS OF ALCOHOLS BY DILUTED HYDROGEN-PEROXIDE UNDER PHASE-TRANSFER CONDITIONS [J].

BORTOLINI, O ;

CONTE, V ;

DIFURIA, F ;

MODENA, G .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (14) :2661-2663

[2] METAL CATALYSIS IN OXIDATION BY PEROXIDES .28. ANIONIC MOLYBDENUM-PICOLINATE N-OXIDO-PEROXO COMPLEX - AN EFFECTIVE OXIDANT OF PRIMARY AND SECONDARY ALCOHOLS IN NONPOLAR-SOLVENTS [J].

BORTOLINI, O ;

CAMPESTRINI, S ;

DIFURIA, F ;

MODENA, G ;

VALLE, G .

JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (24) :5467-5469

[3] STUDIES ON POLYOXO-METALATES AND POLYPEROXO-METALATES .1. TETRAMERIC HETEROPOLYPEROXOTUNGSTATES AND HETEROPOLYPEROXOMOLYBDATES [J].

DENGEL, AC ;

GRIFFITH, WP ;

PARKIN, BC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (18) :2683-2688

[4] PEROXO AND SUPEROXO COMPLEXES OF CHROMIUM, MOLYBDENUM, AND TUNGSTEN [J].

DICKMAN, MH ;

POPE, MT .

CHEMICAL REVIEWS, 1994, 94 (03) :569-584

[5] Catalytic oxidative desulfurization with a hexatungstate/aqueous H2O2/ionic liquid emulsion system [J].

Ding, Yuxiao ;

Zhu, Wenshuai ;

Li, Huaming ;

Jiang, Wei ;

Zhang, Ming ;

Duan, Yuqing ;

Chang, Yonghui .

GREEN CHEMISTRY, 2011, 13 (05) :1210-1216

[6] Heteropolyanion-Based Ionic Liquid for Deep Desulfurization of Fuels in Ionic Liquids [J].

Huang, Wangli ;

Zhu, Wenshuai ;

Li, Huaming ;

Shi, Hua ;

Zhu, Guopeng ;

Liu, Hui ;

Chen, Guangying .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (19) :8998-9003

[7]

Isbii Y, 1988, J ORG CHEM, V53, P3587

[8] OXIDATION OF ALCOHOLS BY MOLYBDENUM AND TUNGSTEN PEROXO COMPLEXES [J].

JACOBSON, SE ;

MUCCIGROSSO, DA ;

MARES, F .

JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (06) :921-924

[9] A dicationic ionic liquid-modified phosphotungstate hybrid catalyst for the heterogeneous oxidation of alcohols with H2O2 [J].

Leng Yan ;

Zhao PingPing ;

Zhang MingJue ;

Chen GuoJian ;

Wang Jun .

SCIENCE CHINA-CHEMISTRY, 2012, 55 (09) :1796-1801

[10] THE MANGANESE-CONTAINING POLYOXOMETALATE, [WZNMN2II(ZNW9O34)(2)](12-), AS A REMARKABLY EFFECTIVE CATALYST FOR HYDROGEN-PEROXIDE MEDIATED OXIDATIONS [J].

NEUMANN, R ;

GARA, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (18) :5066-5074

← 1 2 →