Electrostatic interaction between ionic polymer grafted surfaces studied by atomic force microscopy

被引：11
|
作者：
Zhang, JF [1 ]
Uchida, E [1 ]
Uyama, Y [1 ]
Ikada, Y [1 ]
机构：
[1] KYOTO UNIV,BIOMED ENGN RES CTR,SAKYO KU,KYOTO 606,JAPAN
来源：
JOURNAL OF COLLOID AND INTERFACE SCIENCE | 1997年 / 188卷 / 02期
关键词：
surface graft polymerization; surface force; ionic interaction; atomic force microscopy (AFM);
D O I：
10.1006/jcis.1997.4784
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
To study the electrostatic interaction between two ionic polymer grafted surfaces in aqueous media, an atomic force microscopic tip surface was modified by graft polymerization of a cationic monomer, dimethylaminoethyl methacrylate (DMAEMA), after being coated with a thin layer of cyanoacrylate polymer. A poly(ethylene terephthalate) (PET) film which was the countersurface of the modified tip for the measurement of atomic force microscopy was also modified by surface graft polymerization of DMAEMA and an anionic monomer, acrylic acid (AAc). An appreciable adhesive force was observed in water between the DMAEMA-grafted tip and the AAc grafted PET surface, while a repulsive interaction was noticed between the DMAEMA-grafted tip and the DMAEMA-grafted PET film. Addition of KCl to the medium for the atomic force measurement exhibited a remarkable reduction in the adhesive interaction. These interactions were attributed to the Coulombic force between the grafted ionic polymer chains. (C) 1997 Academic Press.
引用
收藏
页码：431 / 438
页数：8
相关论文
共 50 条
  • [11] Characterization of polymer surfaces with atomic force microscopy
    Magonov, SN
    Reneker, DH
    ANNUAL REVIEW OF MATERIALS SCIENCE, 1997, 27 : 175 - 222
  • [12] Study of polydispersity of grafted polymer surfaces using single molecule atomic force microscopy.
    Al-Maawali, S
    Bemis, JE
    Akhremitchev, BB
    Leecharoen, R
    Janesko, BG
    Walker, GC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U341 - U341
  • [13] Confined polymer melts studied by atomic force microscopy
    Sun, GX
    Kappl, M
    Butt, HJ
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2004, 250 (1-3) : 203 - 209
  • [14] On the formation of oriented nanometer scale patterns on amorphous polymer surfaces studied by atomic force microscopy
    Mat. Sci. and Technology of Polymers, Fac. Chem. Technol., Univ. T., Enschede, Netherlands
    Appl Surf Sci, 3 (147-154):
  • [15] On the formation of oriented nanometer scale patterns on amorphous polymer surfaces studied by atomic force microscopy
    Pickering, JP
    Vancso, GJ
    APPLIED SURFACE SCIENCE, 1999, 148 (3-4) : 147 - 154
  • [16] Polymer dispersions and their interaction with mortar constituents and ceramic tile surfaces studied by zeta-potential measurements and atomic force microscopy
    Kaufmann, Josef
    Winnefeld, Frank
    Zurbriggen, Roger
    CEMENT & CONCRETE COMPOSITES, 2012, 34 (05): : 604 - 611
  • [17] Effect of aluminium sulphate on interactions between silica surfaces studied by atomic force microscopy
    Donose, Bogdan C.
    Nguyen, Anh V.
    Evans, Geoffrey M.
    Yan, Yaode
    WATER RESEARCH, 2007, 41 (15) : 3449 - 3457
  • [18] Strain relaxation at cleaved surfaces studied by atomic force microscopy
    F. Lelarge
    O. Dehaese
    E. Kapon
    C. Priester
    Applied Physics A, 1999, 69 : 347 - 351
  • [19] Quantitative Probing in Atomic Force Microscopy of polymer Surfaces
    Coll. of Egineering and Appl. Sci., Western Michigan University, Kalmazoo, MI 49008, United States
    ACS Symp Ser, (252-265):
  • [20] Hydrogenated diamond surfaces studied by atomic and Kelvin force microscopy
    Rezek, B
    Nebel, CE
    Stutzmann, M
    DIAMOND AND RELATED MATERIALS, 2004, 13 (4-8) : 740 - 745
12345