In situ deposition of graphene nanosheets on wood surface by one-pot hydrothermal method for enhanced UV-resistant ability

被引:26
作者
Wan, Caichao [1 ]
Jiao, Yue [1 ]
Li, Jian [1 ]
机构
[1] Northeast Forestry Univ, Mat Sci & Engn Coll, Harbin 150040, Peoples R China
基金
中国国家自然科学基金;
关键词
Wood; Graphene; Hydrothermal method; Composites; UV resistance; RAMAN-SPECTROSCOPY; CELLULOSE; LIGNIN; PHOTODEGRADATION; POLYMERS; NANOCOMPOSITES; HEMICELLULOSE; DEGRADATION; COMPOSITES; STABILITY;
D O I
10.1016/j.apsusc.2015.04.178
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Graphene nanosheets were successfully in situ deposited on the surface of the wood matrix via a mild fast one-pot hydrothermal method, and the resulting hybrid graphene/wood (GW) were characterized by scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), Raman spectroscopy, and thermogravimetric analysis (TGA). According to the results, the wood matrix was evenly coated by dense uninterrupted multilayer graphene membrane structure, which was formed by layer-by-layer self-assembly of graphene nanosheets. Meanwhile, the graphene coating also induced significant improvement in the thermal stability of GW in comparison with that of the original wood (OW). Accelerated weathering tests were employed to measure and determine the UV-resistant ability of OW and GW. After about six hundred hours of experiments, the surface color change of GW was much less than that of OW; besides, the Fourier transform infrared spectroscopy (FTIR) analysis also proved the less significant changes in surface chemical compositions of GW. The results both indicated that the graphene coating effectively protected wood surface from UV damage. Therefore, this class of GW composite might be expected to be served as high-performance wooden building material for outdoor or some particular harsh environments like strong UV radiation regions use. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:891 / 897
页数:7
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