Metallocene catalysts for olefin oligomerization

被引：52
|
作者：
Janiak, C [1 ]
Blank, F [1 ]
机构：
[1] Univ Freiburg, Inst Anorgan & Anlyt Chem, D-79104 Freiburg, Germany
来源：
MACROMOLECULAR SYMPOSIA | 2006年 / 236卷
关键词：
1-hexene; MALDI MS; metallocene catalysts; oligomers; propene;
D O I：
10.1002/masy.200690047
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Metallocene complexes with a cocatalyst such as methylalumoxane, MAO can be used as catalysts in the dimerization or oligomerization of olefins (alkenes) including the (co-/hydro-)oligomerization of ethene, of the alpha-olefins propene, 1-butene, 1-pentene, 1-hexene, and higher alpha-olefins, branched alpha-olefins, cyclic olefins and alpha,omega-dienes. Possible applications of alpha-olefin oligomers are summarized. Oligo-olefins can be analyzed by gel permeation chromatography (GPC) or H-1 NMR spectroscopy for molecular weight determinations and by H-1 and 13 C NMR spectroscopy or MALDI-TOF mass spectrometry for their end group structure.
引用
收藏
页码：14 / 22
页数：9
相关论文
共 50 条
  • [41] Mechanisms of olefin insertion and alkyl isomerization for metallocene polymerization catalysts
    Bercaw, JE
    Chirik, PJ
    Yoder, JC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 225 : U17 - U17
  • [42] Synthesis of silica-supported metallocene catalysts for olefin polymerization
    Bortolussi, F
    Broyer, JP
    Spitz, R
    Boisson, C
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2002, 203 (17) : 2501 - 2507
  • [43] Synthetic and mechanistic investigations of olefin polymerization with metallocene catalysts.
    Bercaw, JE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 220 : U81 - U81
  • [44] The discovery and evolution of metallocene-based olefin polymerization catalysts
    Kaminsky, Walter
    RENDICONTI LINCEI-SCIENZE FISICHE E NATURALI, 2017, 28 : 87 - 95
  • [45] Anion influence in metallocene-based olefin polymerisation catalysts
    Wilson, PA
    Hannant, MH
    Wright, JA
    Cannon, RD
    Bochmann, M
    MACROMOLECULAR SYMPOSIA, 2006, 236 : 100 - 110
  • [46] METALLOCENE CATALYSTS FOR OLEFIN POLYMERIZATION, STEREOCHEMICAL CONTROL AND POLYMER PROPERTIES
    CHIEN, JCW
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 199 : 599 - INOR
  • [47] New organic supports for metallocene catalysts applied in olefin polymerizations
    Klapper, M
    Jang, YJ
    Bieber, K
    Nemnich, T
    Nenov, N
    Müllen, K
    MACROMOLECULAR SYMPOSIA, 2004, 213 : 131 - 145
  • [48] Composition determination of post-metallocene olefin polymerization catalysts
    V. P. Fadeeva
    V. D. Tikhova
    O. N. Nikulicheva
    I. I. Oleynik
    I. V. Oleynik
    Journal of Structural Chemistry, 2010, 51 (Suppl 1) : 186 - 191
  • [49] Solid acid supported metallocene catalysts for olefin polymerization.
    Suzuki, T
    Suga, Y
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 213 : 114 - POLY
  • [50] Behavior of metallocene olefin polymerization catalysts under high pressure
    Suzuki, N
    Yamaguchi, Y
    Fries, A
    Mise, T
    MACROMOLECULES, 2000, 33 (12) : 4602 - 4606
12345