Selective Retention of Methanol over Ethanol by a Cyclen-Based Cryptand/Copper(II) Complex

被引：13
|
作者：
Habata, Yoichi [1 ,2 ]
Ikeda, Mari [1 ]
Sah, Ajay K. [1 ]
Noto, Kanae [2 ]
Kuwahara, Shunsuke [1 ,2 ]
机构：
[1] Toho Univ, Dept Chem, Fac Sci, Funabashi, Chiba 2748510, Japan
[2] Toho Univ, Res Ctr Mat Integrated Properties, Funabashi, Chiba 2748510, Japan
来源：
INORGANIC CHEMISTRY | 2013年 / 52卷 / 20期
关键词：
PD-CATALYZED AMINATION; AG+-PI INTERACTIONS; AROMATIC SIDE-ARMS; ARGENTIVOROUS MOLECULES; METAL-COMPLEXES; ARTIFICIAL PROTEASES; MACROCYCLIC LIGANDS; FUNCTIONALIZATION; RECOGNITION; DERIVATIVES;
D O I：
10.1021/ic4021417
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A cyclen-based cryptand (2) was prepared in a two-step synthesis from dioxocyclen. When a Cu(CF3SO3)(2) complex with 2 was prepared in methanol, the 2/Cu(CF3SO3)(2) complex incorporated one methanol in the cavity formed by the diethyleneoxy unit and the NH group of the cyclen. When prepared in ethanol, the 2/Cu(CF3SO3)(2) complex similarly incorporated one ethanol. Cold electrospray ionization mass spectrometry (CSI-MS) of the 2/Cu(CF3SO3)(2)/alcohol complexes selectively retains methanol over ethanol under CSI-MS conditions.
引用
收藏
页码：11697 / 11699
页数：3
相关论文
共 50 条
  • [21] ENDOR STUDIES ON THE INTERACTION OF METHANOL WITH COPPER(II) DITHIOPHOSPHATE COMPLEX
    YORDANOV, ND
    ZDRAVKOVA, M
    JOURNAL OF MOLECULAR LIQUIDS, 1992, 53 : 103 - 110
  • [22] Mercury (II)-selective PVC membrane electrodes based on novel cryptand derivatives
    Acar, Pinar
    Oezel, Ayca Demirel
    Canel, Esin
    Ocak, Ummuehan
    Sentuerk, H. Basri
    Goek, Yasar
    Kilic, Esma
    MAIN GROUP METAL CHEMISTRY, 2007, 30 (2-3) : 117 - 133
  • [23] Coupling of methanol and ethanol over CuMgAlOx catalysts: the roles of copper species and alkalinity
    Cheng, Fulong
    Guo, Heqin
    Cui, Jinglei
    Hou, Bo
    Xi, Hongjuan
    Jia, Litao
    Li, Debao
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2019, 126 (01) : 119 - 136
  • [24] Coupling of methanol and ethanol over CuMgAlOx catalysts: the roles of copper species and alkalinity
    Fulong Cheng
    Heqin Guo
    Jinglei Cui
    Bo Hou
    Hongjuan Xi
    Litao Jia
    Debao Li
    Reaction Kinetics, Mechanisms and Catalysis, 2019, 126 : 119 - 136
  • [25] COMPLETE OXIDATION OF ETHANOL, ACETALDEHYDE, AND ETHANOL METHANOL MIXTURES OVER COPPER-OXIDE AND COPPER CHROMIUM-OXIDE CATALYSTS
    RAJESH, H
    OZKAN, US
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1993, 32 (08) : 1622 - 1630
  • [26] Total pressure measurements for copper(II) Chloride + Methanol + Ethanol at 303.15 K
    Department of Chemical Engineering, University of South Florida, Tampa
    FL
    33620-5350, United States
    不详
    Journal of Chemical and Engineering Data, 1995, 40 (02): : 504 - 508
  • [27] Outer-sphere anion recognition by a cyclen-based octadentate europium(III) complex: pH dependent recognition of ortho-phthalic acid
    Sannasy, Desigan
    Marques, Helder M.
    Fernandes, Manuel A.
    de Sousa, Alvaro S.
    CHEMICAL COMMUNICATIONS, 2014, 50 (13) : 1582 - 1584
  • [28] Site-selective ethanol conversion over supported copper catalysts
    Sato, Andre G.
    Volanti, Diogo P.
    de Freitas, Isabel C.
    Longo, Elson
    Bueno, Jose Maria C.
    CATALYSIS COMMUNICATIONS, 2012, 26 : 122 - 126
  • [29] Fluorescence-based detection of nitric oxide in aqueous and methanol media using a copper(II) complex
    Mondal, Biplab
    Kumar, Pankaj
    Ghosh, Pokhraj
    Kalita, Apurba
    CHEMICAL COMMUNICATIONS, 2011, 47 (10) : 2964 - 2966
  • [30] A SELECTIVE SORBENT BASED ON A MESOMORPHOUS COPPER COMPLEX
    KRESTOV, AG
    BLOKHINA, SV
    GALYAMETDINOV, YG
    OLKHOVICH, MV
    JOURNAL OF ANALYTICAL CHEMISTRY, 1993, 48 (09) : 1034 - 1036
12345