Patterning layered polymeric multilayer films by room-temperature nanoimprint lithography

被引:12
|
作者
Lu, YX [1 ]
Hu, W [1 ]
Ma, Y [1 ]
Zhang, LB [1 ]
Sun, JQ [1 ]
Lu, N [1 ]
Shen, JC [1 ]
机构
[1] Jilin Univ, Coll Chem, Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China
关键词
layer-by-layer assembly; lithography; multilayer films; nanoimprint lithography; polyelectrolytes; pattern;
D O I
10.1002/marc.200500834
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polyelectrolyte multilayer films of poly(acrylic acid) (PAA)/poly(allylamine hydrochloride) (PAH) and PAH/ poly(sodium 4-styrenesulfonate) (PSS) based on electrostatic interactions as a driving force are patterned by room-temperature nanoimprint lithography (RT-NIL). Under an imprinting pressure of 40 bar for 8 min, well-defined pattern structures with a line width of approximate to 330 nm and a separation of approximate to 413 nm are achieved. Meanwhile, hydrogen-bonding-directed multilayer films of poly(vinyl pyrrolidone) (PVPON)/ poly(methyl acrylic acid) (PMAA) and poly(4-vinylpyridine)/ PAA can also be patterned in a similar way by RT-NIL. The successful imprinting of these films originates from the high compressibility and fluidity of the layered polymeric films under high pressure.
引用
收藏
页码:505 / 510
页数:6
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