Chloride ion sites in silicate and aluminosilicate glasses:: A preliminary study by 35Cl solid-state NMR

被引：0

作者：

Stebbins, JF ^{[1
]}

Du, LS ^{[1
]}

机构：

[1] Stanford Univ, Dept Geol & Environm Sci, Stanford, CA 94305 USA

来源：

AMERICAN MINERALOGIST | 2002年 / 87卷 / 2-3期

关键词：

D O I：

暂无

中图分类号：

P3 [地球物理学]; P59 [地球化学];

学科分类号：

0708 ; 070902 ;

摘要：

Despite the importance of the chloride ion in magmas and the fluids that separate from them, very little is known about atomic-scale structural environments for Cl in silicate glasses. We present here the first solid-state Cl-35 NMR data for Cl in silicate and aluminosilicate glasses, made possible by the availability of very high (14.1 to 18.8 Tesla) magnetic fields., We find that Cl-35 has a wide range in chemical shifts that correlate well with cation-Cl distance and thus contain considerable structural information. In general, Cl is coordinated primarily by network-modifying alkali or alkaline earth cations, and we see no evidence for Al-Cl bonding.

引用

页码：359 / 363

页数：5

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