Effects of Addition of Layered Double Hydroxide to Air Electrodes for Metal-Air Batteries

被引：3

作者：

Miyazaki, Kohei ^{[1
,2
]}

Nishio, Koji ^{[1
]}

Abe, Takeshi ^{[1
]}

Suto, Koji ^{[3
]}

Kotani, Yukinari ^{[3
]}

Nakanishi, Shinji ^{[3
]}

Ogumi, Zempachi ^{[4
]}

机构：

[1] Kyoto Univ, Dept Energy & Hydrocarbon Chem, Nishikyo Ku, Kyoto 6158510, Japan

[2] Japan Sci & Technol Agcy, PRESTO, Kawaguchi, Saitama 3320012, Japan

[3] Toyota Motor Co Ltd, Battery Res Div, Shizuoka 4101193, Japan

[4] Kyoto Univ, Off Soc Acad Collaborat Innovat, Kyoto 6110011, Japan

来源：

ELECTROCHEMISTRY | 2012年 / 80卷 / 10期

关键词：

Metal-Air Batteries; Layered Double Hydroxides; Perovskite-Type Oxides; Oxygen Reduction Reaction;

D O I：

10.5796/electrochemistry.80.728

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

In order to improve oxygen reduction performances of an air electrode using perovskite type La0.7Ca0.3CoO3 as an electrocatalyst, a layered double hydroxide (LDH) containing magnesium and aluminum was examined as an ion-conducting additive. Although the addition of LDH impeded gas permeation of the catalyst layer of the electrode, it was effective in reducing charge transfer resistance of the electrode, and as a result, the oxygen reduction reaction of the air electrode was remarkably enhanced. (C) The Electrochemical Society of Japan, All rights reserved.

引用

页码：728 / 730

页数：3

共 14 条

[1] Recent developments in polymer electrolyte fuel cell electrodes [J].

Antolini, E .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 2004, 34 (06) :563-576

[2] Metal-air batteries: from oxygen reduction electrochemistry to cathode catalysts [J].

Cheng, Fangyi ;

Chen, Jun .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (06) :2172-2192

[3] A Critical Review of Li/Air Batteries [J].

Christensen, Jake ;

Albertus, Paul ;

Sanchez-Carrera, Roel S. ;

Lohmann, Timm ;

Kozinsky, Boris ;

Liedtke, Ralf ;

Ahmed, Jasim ;

Kojic, Aleksandar .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2012, 159 (02) :R1-R30

[4] Reversible air electrodes integrated with an anion-exchange membrane for secondary air batteries [J].

Fujiwara, Naoko ;

Yao, Masaru ;

Siroma, Zyun ;

Senoh, Hiroshi ;

Ioroi, Tsutomu ;

Yasuda, Kazuaki .

JOURNAL OF POWER SOURCES, 2011, 196 (02) :808-813

[5]

Haas O, 2009, ENCY ELECTROCHEMICAL, P384

[6] Surface Properties and Electrochemical Performance of Carbon Materials for Air Electrodes of Lithium-Air Batteries [J].

Hayashi, Masahiko ;

Minowa, Hironobu ;

Takahashi, Masaya ;

Shodai, Takahisa .

ELECTROCHEMISTRY, 2010, 78 (05) :325-328

[7]

Itagaki M., 2008, DENKIKAGAKU IMPEDANC

[8] A novel synthetic route to layered double hydroxides using hexamethylenetetramine [J].

Iyi, N ;

Matsumoto, T ;

Kaneko, Y ;

Kitamura, K .

CHEMISTRY LETTERS, 2004, 33 (09) :1122-1123

[9] Bifunctional oxygen/air electrodes [J].

Jörissen, L .

JOURNAL OF POWER SOURCES, 2006, 155 (01) :23-32

[10] Review on Li-air batteries-Opportunities, limitations and perspective [J].

Kraytsberg, Alexander ;

Ein-Eli, Yair .

JOURNAL OF POWER SOURCES, 2011, 196 (03) :886-893

← 1 2 →