Novel 1,2-3,4-Bridged and 1,3-Bridged Calix[4]arene Based on Large s-triazine Conjugate Systems: Synthesis and Complexation for Dyes

被引：12
作者：
Bai, Xiaoyan [1 ]
Yang, Fafu [1 ,2 ]
Xie, Jianwei [1 ]
Guo, Hongyu [1 ]
机构：
[1] Fujian Normal Univ, Coll Chem & Mat, Fuzhou 350007, Peoples R China
[2] Fujian Key Lab Polymer Mat, Fuzhou, Peoples R China
来源：
JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY | 2013年 / 50卷 / 03期
基金：
中国国家自然科学基金;
关键词：
Calix[4]arene; bridging; triazine; complexation; dye; EXTRACTION PROPERTIES; ARENE; BISCALIXARENE; RECEPTORS; RIM; ION;
D O I：
10.1080/10601325.2013.755884
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Two novel 1,2-3,4-bridged and 1,3-bridged calix[4]arenes 6 and 9 based on large s-triazine conjugate systems were designed and synthesized in high yields. The liquid-liquid extraction experiment showed that they possessed excellent extraction abilities towards one cationic and three anionic dyes [Orange I (OI), Methylene blue (MB), Neutral red (NR), Brilliant green (BG)]. The highest extraction percentage of compound 9 was 91.2% for BG. The complexation UV-Vis spectra of compounds 6 and 9 with four dyes indicated the existence of complexation action between hosts and guests with 1:1 ratio of complexation in DMSO solution. The association constants suggested that the 1,2-3,4-bridging structure was more favorable for producing excellent complexation abilities than 1,3-bridging structure. The association constant of compound 9 with BG was as high as 4.5 x 10(6) M-1.
引用
收藏
页码：334 / 339
页数：6
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