Room temperature solid state reaction involving structural transformation of covalent oxide network

被引：3

作者：

Eda, K ^{[1
]}

Fukiharu, S ^{[1
]}

Suzuki, T ^{[1
]}

Sotani, N ^{[1
]}

机构：

[1] Kobe Univ, Fac Sci, Dept Chem, Nada Ku, Kobe, Hyogo 6578501, Japan

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2002年 / 164卷 / 01期

关键词：

solid state reaction; room temperatures reaction; transformation of covalent oxide network; Mo-O system;

D O I：

10.1006/jssc.2001.9465

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An interesting structural transformation from a two-dimensional (2d) covalent oxide network with a layered structure to a three-dimensional (3d) network with a tunnel structure was found at room temperature in the mixture of hydrated alkali-metal molybdenum bronze and amorphous alkali-metal molybdate. From various experimental results it was concluded that the transformation was due to a room temperature solid state reaction. (C) 2002 Elsevier Science (USA).

引用

页码：157 / 162

页数：6

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