{[Dy2(bpdc)3(H2O)3] • H2O}n (bpdc=2,2′-bipyridine-4,4′-dicarboxylate): A highly-thermostable 3D coordination polymer with unusual mixed-connected network topology

被引:24
作者
Fu, Feng [1 ,2 ]
Li, Dong-Sheng [1 ,2 ]
Zhang, Cui-Qiao [1 ]
Wang, Ji-Jiang [1 ]
Wu, Ya-Pan [1 ]
Du, Miao [3 ]
Wang, Ji-Wu [1 ]
机构
[1] Yanan Univ, Coll Chem & Chem Engn, Shaanxi Key Lab Chem React Engn, Yanan 716000, Peoples R China
[2] Three Gorges Univ, Coll Mech & Mat Engn, Yichang 443002, Peoples R China
[3] Tianjin Normal Univ, Coll Chem & Life Sci, Tianjin 300387, Peoples R China
基金
中国国家自然科学基金;
关键词
Coordination polymer; Network topology; Thermal stability; Luminescent property;
D O I
10.1016/j.inoche.2008.07.021
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel 3D coordination polymer ([Dy-2(bpdc)(3)(H2O)(3)] center dot H2O)(n) (bpdc = 2,2'-bipyridine-4,4'-dicarboxylate) based on inorganic rod-shaped infinite secondary building unit is presented, which possesses unusual mixed-connected network topology and shows high thermal stability and strong photoluminescence at room temperature. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:1260 / 1263
页数:4
相关论文
共 51 条
[1]  
Batten SR, 2000, CHEM-EUR J, V6, P156, DOI 10.1002/(SICI)1521-3765(20000103)6:1<156::AID-CHEM156>3.0.CO
[2]  
2-Y
[3]  
Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO
[4]  
2-Z
[5]   Inorganic crystal engineering using self-assembly of tailored building-blocks [J].
Blake, AJ ;
Champness, NR ;
Hubberstey, P ;
Li, WS ;
Withersby, MA ;
Schröder, M .
COORDINATION CHEMISTRY REVIEWS, 1999, 183 :117-138
[6]   Coordination bonds and strong hydrogen bonds giving a framework material based on a 4-and 8-connected net in [Ca[Co(en)(oxalato)2]2]n [J].
Borel, Cedric ;
Hakansson, Mikael ;
Ohrstrom, Lars .
CRYSTENGCOMM, 2006, 8 (09) :666-669
[7]   NOVEL NETWORKS OF UNUSUALLY COORDINATED SILVER(I) CATIONS - THE WAFER-LIKE STRUCTURE OF [AG(PYZ)(2)][AG-2(PYZ)(5)](PF6)(3)CENTER-DOT-2G AND THE SIMPLE CUBIC FRAME OF [AG(PYZ)(3)](SBF6) [J].
CARLUCCI, L ;
CIANI, G ;
PROSERPIO, DM ;
SIRONI, A .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (17) :1895-1898
[8]   Design of frameworks with mixed triangular and octahedral building blocks exemplified by the structure of [Zn4O(TCA)2] having the pyrite topology [J].
Chae, HK ;
Kim, J ;
Friedrichs, OD ;
O'Keefe, M ;
Yaghi, OM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (33) :3907-3909
[9]   Interwoven metal-organic framework on a periodic minimal surface with extra-large pores [J].
Chen, BL ;
Eddaoudi, M ;
Hyde, ST ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2001, 291 (5506) :1021-1023
[10]   A 3D heteropolynuclear network with 4,6-connected (44•62)(48•66•8) topology:: Synthesis, structure, thermal and magnetic properties [J].
Chen, Pang-Kuan ;
Che, Yun-Xia ;
Zheng, Ji-Min .
INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (02) :187-190