An α-{P2W18O62}6--Based Supramolecular Hybrid Inorganic-Organic Compound with Visible Light-Driven Photocatalytic Properties

被引：1
|
作者：
Zhu, Xiaofei [1 ]
Yang, Yu [1 ]
Jiang, Ni [2 ]
Li, Bo [2 ]
Fu, Hai [1 ]
Yin, Zifan [1 ]
Yang, Jun [1 ]
机构：
[1] Changchun Univ Technol, Sch Chem & Life Sci, Changchun 130012, Jilin, Peoples R China
[2] North China Univ Sci & Technol, Coll Publ Hlth, Coll Mat Sci & Engn, Hebei Prov Key Lab Inorgan Nonmetall Mat, Tangshan 063009, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2016年 / 642卷 / 19期
基金：
中国国家自然科学基金;
关键词：
Coordination polymer; Crystal structure; Visible light; Photocatalytic properties; Tungsten; WELLS-DAWSON POLYOXOMETALATE; COORDINATION POLYMER; FRAMEWORK MATERIALS; HYDROGEN EVOLUTION; POLYOXOANION; COMPLEXES; CRYSTAL;
D O I：
10.1002/zaac.201600194
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The alpha-[P2W18O62](6-)-based coordination polymer [Cu-2(phen)(3)(H2O)(3)(P2W18O62)][Cu(phen)(2)(H2O)]center dot 5H(2)O (1) (phen = phenanthroline), was hydrothermally synthesized and characterized by single-crystal and powder X-ray diffraction, IR and UV/Vis diffuse reflection spectroscopy, and elemental analysis. Structural studies reveal that compound 1 exhibits a three-dimensional (3D) supramolecular structure based on pi-pi and hydrogen bonding interactions. In addition, visible light driven photocatalytic experiments of compound 1 were also studied.
引用
收藏
页码：1091 / 1094
页数：4
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