Experimental preparation and UV/IR spectroscopic characterization of 1,3-dibutanal-1,2,4,5-tetroxane

被引：4

作者：

Ayala, D. A.

Romero, J. M.

Jorge, N. L.

Gomez-Vara, M. E.

Jubert, A. H.

Castro, E. A.

机构：

[1] Univ Nacl Nordeste, Area Fisicoquim, FACENA, RA-3400 Corrientes, Argentina

[2] UNLP, Fac Ciencias Exactas, CEQUINOR, Dept Quim, RA-1900 La Plata, Buenos Aires, Argentina

[3] UNLP, Fac Ingn, CEQUINOR, Dept Quim, RA-1900 La Plata, Buenos Aires, Argentina

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2006年 / 64卷 / 03期

关键词：

1,3-dibutanal-1,2,4,5-tetroxane; UV and IR spectroscopy; tetroxane derivatives; theoretical calculation;

D O I：

10.1016/j.saa.2005.06.046

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

We report the experimental preparation of the 1,3-butanal-1,2,4,5-tetroxane by oxidation of glutataldehyde with oxygen peroxide in presence of concentrated sulfuric acid, following the Bayer and Viller method modified by Jorge et al. The UV and IR spectra are studied from the experimental and theoretical standpoint. A rather complete vibrational assignment was performed and the nature of the electronic transitions was discussed in detail. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：717 / 721

页数：5

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