Synthesis and Properties of C2h-Symmetric BN-Heteroacenes Tailored through Aromatic Central Cores

被引：46

作者：

Wang, Xinyang ^{[1
]}

Zhang, Fan ^{[1
]}

Gao, Jianhua ^{[2
]}

Fu, Yubin ^{[1
,3
,4
]}

Zhao, Wuxue ^{[1
]}

Tang, Ruizhi ^{[1
]}

Zhang, Wanzheng ^{[1
]}

Zhuang, Xiaodong ^{[1
]}

Feng, Xinliang ^{[1
,3
,4
]}

机构：

[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China

[2] Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 311121, Zhejiang, Peoples R China

[3] Tech Univ Dresden, Ctr Adv Elect Dresden Cfaed, D-01062 Dresden, Germany

[4] Tech Univ Dresden, Dept Chem & Food Chem, D-01062 Dresden, Germany

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 80卷 / 20期

关键词：

C-C; SEMICONDUCTORS; STABILITY; ACENES;

D O I：

10.1021/acs.joc.5b01718

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 2-fold successive electrophilic borylation on one aromatic central core led to a series of C-2h-symmetric BN-heteroacenes in excellent yields. For the first time, we introduced trimethylsilyl (TMS) as either leaving group or oriented group for efficiently improving the preparation of BN-embedded polycyclic aromatic hydrocarbons (PAHs). The physical properties of the as-synthesized BN-heteroacenes in either solid state or solution can be finely tuned through the position isomerization or the fused ring numbers of the aromatic central core.

引用

页码：10127 / 10133

页数：7

共 31 条

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