Preparation of thiol-ene porous polymers by emulsion templating

被引:26
|
作者
Sergent, Benoit [1 ]
Birot, Marc [1 ]
Deleuze, Herve [1 ]
机构
[1] Univ Bordeaux, Inst Mol Sci, CNRS, UMR 5255, F-33405 Talence, France
关键词
polyHIPE; Thiol-ene polymerization; Monolith; SOLUBLE POROGENIC SOLVENTS; SURFACE-AREA; FOAMS; POLYHIPE; POLYMERIZATION; MORPHOLOGY; DIVINYLBENZENE; CHEMISTRY; CHLORIDE; HIPES;
D O I
10.1016/j.reactfunctpolym.2012.02.011
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Emulsion-templated porous polymeric materials are prepared by thermal thiol-ene reaction. The right choice of a non-methacrylate trivinyl monomer allows obtaining rigid monoliths with a total porosity of 80% and having the expected polyHIPE morphology. (c) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:962 / 966
页数:5
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