Recent Advancement of the thio-Claisen Rearrangement

被引：9

作者：

Majumdar, Krishna C. ^{[1
,2
]}

Samanta, Srikanta ^{[1
]}

Chattopadhyay, Buddhadeb ^{[1
]}

Pal, Nilasish ^{[1
]}

机构：

[1] Univ Kalyani, Dept Chem, Kalyani 741235, WB, India

[2] Tezpur Univ, Dept Chem Sci, Tezpur 784028, Assam, India

来源：

CURRENT ORGANIC SYNTHESIS | 2012年 / 9卷 / 06期

关键词：

Thio-Claisen rearrangement; thermal Claisen-rearrangement; catalyzed-Claisen rearrangement; asymmetric rearrangement; sulfur heterocycles; regioselective synthesis; stereoselective synthesis; electrocyclization; 3,3]-sigmatropic shift; cyclodextrin; dihydroflustramine C; sequential Claisen rearrangement; Rh-2((S)-tbsp)(4); GAMMA; DELTA-UNSATURATED AMINO-ACIDS; FACILE REGIOSELECTIVE SYNTHESIS; QUATERNARY SUBSTITUTED THIOINDOLINES; SIGMATROPIC REARRANGEMENT; SULFUR HETEROCYCLES; DIASTEREOSELECTIVE SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; PENTACYCLIC HETEROCYCLES; BIOACTIVE HETEROCYCLES;

D O I：

10.2174/157017912803901682

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This brief review deals with the recent progress in the implimentation of thio-Claisen rearrangement in synthetic organic chemistry. Thio-Claisen rearrangement has been utilized for the synthesis of many heterocyclic moieties of biological significance. Stereoselectivity of the thio-Claisen rearrangement has also been discussed. This short report mainly covers the literature published during 2003 onwards.

引用

页码：851 / 872

页数：22

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