Recent Advancement of the thio-Claisen Rearrangement

被引：9
作者：
Majumdar, Krishna C. [1 ,2 ]
Samanta, Srikanta [1 ]
Chattopadhyay, Buddhadeb [1 ]
Pal, Nilasish [1 ]
机构：
[1] Univ Kalyani, Dept Chem, Kalyani 741235, WB, India
[2] Tezpur Univ, Dept Chem Sci, Tezpur 784028, Assam, India
来源：
CURRENT ORGANIC SYNTHESIS | 2012年 / 9卷 / 06期
关键词：
Thio-Claisen rearrangement; thermal Claisen-rearrangement; catalyzed-Claisen rearrangement; asymmetric rearrangement; sulfur heterocycles; regioselective synthesis; stereoselective synthesis; electrocyclization; 3,3]-sigmatropic shift; cyclodextrin; dihydroflustramine C; sequential Claisen rearrangement; Rh-2((S)-tbsp)(4); GAMMA; DELTA-UNSATURATED AMINO-ACIDS; FACILE REGIOSELECTIVE SYNTHESIS; QUATERNARY SUBSTITUTED THIOINDOLINES; SIGMATROPIC REARRANGEMENT; SULFUR HETEROCYCLES; DIASTEREOSELECTIVE SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; PENTACYCLIC HETEROCYCLES; BIOACTIVE HETEROCYCLES;
D O I：
10.2174/157017912803901682
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This brief review deals with the recent progress in the implimentation of thio-Claisen rearrangement in synthetic organic chemistry. Thio-Claisen rearrangement has been utilized for the synthesis of many heterocyclic moieties of biological significance. Stereoselectivity of the thio-Claisen rearrangement has also been discussed. This short report mainly covers the literature published during 2003 onwards.
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页码：851 / 872
页数：22
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