Expanded hexadentate ligands of Jager type:: synthesis and X-ray analysis

被引:2
作者
Wagner, J [1 ]
Görls, H [1 ]
Keutel, H [1 ]
机构
[1] Univ Jena, Inst Inorgan & Analyt Chem, D-07743 Jena, Germany
关键词
hexadentate ligand; expanded ligand; Schiff based; demetallation; X-ray analysis;
D O I
10.1016/S1387-7003(01)00352-5
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The free ligand 2 of Jager type was synthesized via demetallation of the copper complex 1, 2 was expanded by condensation with dicarbonyl compounds to yield further hexadentate ligands with [N4O2]-donorset suitable for transition metal complexation. The structures of 2 and 3 were described by NMR and X-ray analysis. (C) 2002 Published by Elsevier Science B.V.
引用
收藏
页码:78 / 81
页数:4
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