Polymer blend of PLA/PHBV based bionanocomposites reinforced with nanocrystalline cellulose for potential application as packaging material

被引：95
作者：
Dasan, Y. K. [1 ]
Bhat, A. H. [1 ]
Faiz, Ahmad [2 ]
机构：
[1] Univ Teknol PETRONAS, Dept Fundamental & Appl Sci, Bandar Seri Iskandar 32610, Perak, Malaysia
[2] Univ Teknol PETRONAS, Dept Chem Engn, Bandar Seri Iskandar 32610, Perak, Malaysia
来源：
CARBOHYDRATE POLYMERS | 2017年 / 157卷
关键词：
Nanocrystalline cellulose; Bionanocomposites; Solution casting; Flexural; Morphology; Permeability; MECHANICAL-PROPERTIES; BARRIER PROPERTIES; FIBER; OIL; NANOCOMPOSITES; COMPOSITES; EXTRACTION; NANOCELLULOSE; NANOWHISKERS; DISPERSION;
D O I：
10.1016/j.carbpol.2016.11.012
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The current research discusses the development of poly (lactic acid) (PLA) and poly-(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) reinforced nanocrystalline cellulose bionanocomposites. The nanocrystalline cellulose was derived from waste oil palm empty fruit bunch fiber by acid hydrolysis process. The resulting nanocrystalline cellulose suspension was then surface functionaliied by TEMPO-mediated oxidation and solvent exchange process. Furthermore, the PLAIPHBV/nanocrystalline cellulose bionanocomposites were produced by solvent casting method. The effect of the addition of nanocrystalline cellulose on structural, morphology, mechanical and barrier properties of bionanocomposites was investigated. The results revealed that the developed bionanocomposites showed improved mechanical properties and decrease in oxygen permeability rate. Therefore, the developed bio-based composite incorporated with an optimal composition of nanocrystalline cellulose exhibits properties as compared to the polymer blend. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1323 / 1332
页数：10
相关论文
共 67 条
[11]   Biocomposites reinforced with cellulose nanocrystals derived from potato peel waste [J].
Chen, D. ;
Lawton, D. ;
Thompson, M. R. ;
Liu, Q. .
CARBOHYDRATE POLYMERS, 2012, 90 (01) :709-716
[12]  
dos SantosFA., 2016, MAT SCI APPL, V7, P257, DOI [DOI 10.4236/MSA.2016.75026, 10.4236/msa.2016.75026]
[13]   Nanocellulose: a new ageless bionanomaterial [J].
Dufresne, Alain .
MATERIALS TODAY, 2013, 16 (06) :220-227
[14]   Processing of Polymer Nanocomposites Reinforced with Polysaccharide Nanocrystals [J].
Dufresne, Alain .
MOLECULES, 2010, 15 (06) :4111-4128
[15]   Isolation, preparation, and characterization of nanofibers from oil palm empty-fruit-bunch (OPEFB) [J].
Fahma, Farah ;
Iwamoto, Shinichiro ;
Hori, Naruhito ;
Iwata, Tadahisa ;
Takemura, Akio .
CELLULOSE, 2010, 17 (05) :977-985
[16]   Regular Linking of Cellulose Nanocrystals via Click Chemistry: Synthesis and Formation of Cellulose Nanoplatelet Gels [J].
Filpponen, Ilari ;
Argyropoulos, Dimitris S. .
BIOMACROMOLECULES, 2010, 11 (04) :1060-1066
[17]   Extraction and characterization of cellulose nanocrystals from agro-industrial residue - Soy hulls [J].
Flauzino Neto, Wilson Pires ;
Silverio, Hudson Alves ;
Dantas, Noelio Oliveira ;
Pasquini, Daniel .
INDUSTRIAL CROPS AND PRODUCTS, 2013, 42 :480-488
[18]   Properties of polylactic acid composites reinforced with oil palm biomass microcrystalline cellulose [J].
Haafiz, M. K. Mohamad ;
Hassan, Azman ;
Zakaria, Zainoha ;
Inuwa, I. M. ;
Islam, M. S. ;
Jawaid, M. .
CARBOHYDRATE POLYMERS, 2013, 98 (01) :139-145
[19]   Isolation and characterization of microcrystalline cellulose from oil palm biomass residue [J].
Haafiz, M. K. Mohamad ;
Eichhorn, S. J. ;
Hassan, Azman ;
Jawaid, M. .
CARBOHYDRATE POLYMERS, 2013, 93 (02) :628-634
[20]   TEMPO-mediated surface oxidation of cellulose whiskers [J].
Habibi, Youssef ;
Chanzy, Henri ;
Vignon, Michel R. .
CELLULOSE, 2006, 13 (06) :679-687
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