Enhanced two-photon absorption cross-sections of zinc(II) tetraphenylporphyrins peripherally substituted with d6-metal alkynyl complexes

被引：23

作者：

Drouet, Samuel ^{[2
]}

Merhi, Areej ^{[3
]}

Grelaud, Guillaume ^{[1
,2
]}

Cifuentes, Marie P. ^{[1
]}

Humphrey, Mark G. ^{[1
]}

Matczyszyn, Katarzyna ^{[4
]}

Samoc, Marek ^{[4
,5
]}

Toupet, Loic ^{[6
]}

Paul-Roth, Christine O. ^{[2
,3
]}

Paul, Frederic ^{[2
]}

机构：

[1] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia

[2] Univ Rennes 1, UMR CNRS 6226, Inst Sci Chim Rennes, F-35042 Rennes, France

[3] Univ Europeenne Bretagne, INSA Rennes, INSA ISCR UMR 6226, F-35043 Rennes, France

[4] Wroclaw Univ Technol, Inst Phys & Theoret Chem, PL-50370 Wroclaw, Poland

[5] Australian Natl Univ, Laser Phys Ctr, Canberra, ACT 0200, Australia

[6] Univ Rennes 1, UMR CNRS 6251, IPR, F-35042 Rennes, France

来源：

NEW JOURNAL OF CHEMISTRY | 2012年 / 36卷 / 11期

基金：

澳大利亚研究理事会;

关键词：

NONLINEAR-OPTICAL PROPERTIES; CONJUGATED PORPHYRIN DIMERS; IRON SIGMA-ACETYLIDES; STATES; MODEL; NMR;

D O I：

10.1039/c2nj40589j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The syntheses of new Zn(II) tetraphenylporphyrin (ZnTPP) derivatives functionalized with electron-rich d(6)-transition metal alkynyl complexes at their periphery are reported. Z-scan measurements reveal remarkably large effective two-photon absorption (TPA) cross-sections in the visible range for these compounds.

引用

页码：2192 / 2195

页数：4

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