Anion directed control of supramolecular structure in silver complexes through weak interactions

被引:26
作者
Gulbransen, Jayne L. [1 ]
Fitchett, Christopher M. [1 ]
机构
[1] Univ Canterbury, Coll Sci, Dept Chem, Christchurch 8140, New Zealand
来源
CRYSTENGCOMM | 2012年 / 14卷 / 17期
关键词
HYDROGEN-BONDING INTERACTIONS; CHIRAL HETEROCYCLIC LIGANDS; COORDINATION NETWORKS; SULFATE ANION; PI-STACKING; POLYMERS; RECOGNITION; DERIVATIVES; CRYSTAL; 2,2-BIIMIDAZOLE;
D O I
10.1039/c2ce25733e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The control of supramolecular structure through weak interacting anions has been demonstrated in a series of three crystal structures of silver complexes with N,N'-dimethylene-2,2'-biimidazole (L). Progression towards a weakly coordinating anion (PF6-) allows ligand twisting to dominate structure formation.
引用
收藏
页码:5394 / 5397
页数:4
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