Anion directed control of supramolecular structure in silver complexes through weak interactions

被引：26

作者：

Gulbransen, Jayne L. ^{[1
]}

Fitchett, Christopher M. ^{[1
]}

机构：

[1] Univ Canterbury, Coll Sci, Dept Chem, Christchurch 8140, New Zealand

来源：

CRYSTENGCOMM | 2012年 / 14卷 / 17期

关键词：

HYDROGEN-BONDING INTERACTIONS; CHIRAL HETEROCYCLIC LIGANDS; COORDINATION NETWORKS; SULFATE ANION; PI-STACKING; POLYMERS; RECOGNITION; DERIVATIVES; CRYSTAL; 2,2-BIIMIDAZOLE;

D O I：

10.1039/c2ce25733e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The control of supramolecular structure through weak interacting anions has been demonstrated in a series of three crystal structures of silver complexes with N,N'-dimethylene-2,2'-biimidazole (L). Progression towards a weakly coordinating anion (PF6-) allows ligand twisting to dominate structure formation.

引用

页码：5394 / 5397

页数：4

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