Recent developments in enantioselective photocatalysis

被引：74

作者：

Prentice, Callum ^{[1
]}

Morrisson, James ^{[2
]}

Smith, Andrew D. ^{[1
]}

Zysman-Colman, Eli ^{[1
]}

机构：

[1] Univ St Andrews, Organ Semicond Ctr, EaStCHEM, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[2] AstraZeneca, Pharmaceut Sci, IMED Biotech Unit, Macclesfield SK102NA, Cheshire, England

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 16卷

关键词：

enantioenrichment; enantionselective catalysis; enantioselective photocatalysis; photocatalysis; photochemistry; LEWIS-ACID CATALYSIS; 2+2 PHOTOCYCLOADDITION REACTIONS; ANTI-MARKOVNIKOV HYDROETHERIFICATION; COOPERATIVE PHOTOREDOX CATALYSIS; N-HETEROCYCLIC CARBENE; ALPHA-ALKYLATION; DUAL-CATALYSIS; C(SP(3))-H FUNCTIONALIZATION; PHOTOCHEMICAL ACTIVITY; MERGING PHOTOREDOX;

D O I：

10.3762/bjoc.16.197

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantioselective photocatalysis has rapidly grown into a powerful tool for synthetic chemists. This review describes the various strategies for creating enantioenriched products through merging enantioselective catalysis and photocatalysis, with a focus on the most recent developments and a particular interest in the proposed mechanisms for each. With the aim of understanding the scope of each strategy, to help guide and inspire further innovation in this field.

引用

页码：2363 / 2441

页数：79

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