Coordination modulation induced and ultrasonic-assisted synthesis of size-controlled microporous metal-imidazolate framework crystals with enhanced adsorption performance

被引：23
作者：
Liu, Qing [1 ]
Jin, Li-Na [1 ]
Sun, Wei-Yin [1 ]
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing Natl Lab Microstruct,Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China
来源：
CRYSTENGCOMM | 2013年 / 15卷 / 41期
基金：
中国国家自然科学基金;
关键词：
ORGANIC FRAMEWORKS; POLYMER;
D O I：
10.1039/c3ce41133h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Size-controlled metal-imidazolate framework crystals have been synthesized by combining the coordination modulation method and ultrasonic-assisted synthesis for the first time. Aqueous ammonia was used as the coordination modulator, and was found to be able to control the crystal size. The as-obtained crystals had improved adsorption properties compared with that of the bulk ones.
引用
收藏
页码：8250 / 8254
页数：5
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